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Another greatly simplified model, corresponding to a certain degree to globular proteins, considers the polyion as a spherically symmetrical charge cloud The electrostatic contribution to the excess Gibbs energy affects the thermodynamic, rheological, transport, and other properties of polyelectrolytes Here, only dissociation equilibria will be considered briefly Consider a molecule of a carboxylic polyacid with degree of polymerization N, bearing N ionizable groups, n of which are actually ionized K'n is the dissociation constant for the ionization of an acidic group bound to an n-times ionized molecule; K^ is the dissociation constant of the group that splits off the first proton and therefore has not yet been affected by the electric field of the other already ionized groups The expression kT\n KQ gives the Gibbs energy change due to ionization of a neutral molecule.



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If new updates are received from their directly attached neighbors, Routers R2 and R3 build their respective RIBs and then propagate this information to other neighbors. note that a router would not advertise the route back to the neighbor it received the update from. Figure 8.5 illustrates new updates sent from Routers R2 and R3 to Router R1 so that R1 will update its RIB. In Figure 8.6, Router R1 takes the information from the RIB and generates a routing table. Using an algorithm, Router R1 will calculate the best path to a particular network. The parameter that is used in the algorithm to differentiate between two advertisements about the same network from two different neighbors is referred to as the metric or cost. In this example, the metric is the hop count or the number of hops that the destination network is from the source R1. Hop count is a very commonly used metric for distance vector routing protocols.





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The value of kT\nK'n differs from this expression by the electric work necessary for removal of a further proton from the field of an n-fold ionized molecule If the electric charge of an rt-times ionized molecule is AG^, this work is equal to dG^/dn Then we have -kT In K'n = -kT In K'Q + ~ (1519) dn Except at the first stage in neutralization titration, ie for small values of n, all the molecules in solution are found experimentally to be ionized to the same degree a = n/N Then.

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Figure 8.5 If there are changes to the routing information on R2 and R3, they will send new updates to R1. R1 will enter this new information into the RIB and then recalculate a new routing table.

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Information sent from R2 to R1 Dest. Prefix 172.16.1.0/24 192.168.10.10/32 10.10.3.0/30 172.16.2.0/24 192.168.30.30/32 Next-Hop to Net A system Local Local 10.10.1.2 10.10.3.2 10.10.3.2 10.10.1.2 10.10.3.2 Metric 0 0 0 0 1 1 1 1 1 Information sent from R3 to R1 Dest. Prefix 172.16.1.0/24 192.168.10.10/32 10.10.1.0/30 192.168.20.20/32 Next-Hop 10.10.3.2 10.10.3.2 10.10.3.2 10.10.3.2 Metric 2 2 2 2 Next-Hop 10.10.1.2 10.10.1.2 10.10.1.2 10.10.1.2 10.10.1.2 Metric 2 2 2 2 2

Thus, the dissociation equilibrium is affected by the ionic strength, temperature and dielectric constant of the solvent as well as by the parameter h (involved in AGfj). On the other hand, the term dG^/dn does not depend on the degree of polymerization (except for very small values of n). The degree of polymerization does not affect, for example, the course of the potentiometric titration of a poly acid. For a dibasic poly acid, where, of the total of T units, nx are ionized to the V first stage and n2 to the second stage, then simultaneously

Existing RIB on R1 Dest. Prefix 172.16.1.0/24 192.168.10.10/32 10.10.1.0/30 10.10.3.0/30 10.10.2.0/30 10.10.2.0/30 172.16.2.0/24 192.168.20.20/32 192.168.30.30/32

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2(n 2 +l)

Figure 8.6 R1 will scan the RIB and calculate the best route to each network prefix. In this case, it chooses the best route based on the metric. Note that R1 s routing table has only a single entry for each network prefix, while the RIB has multiple entries for many of the prefixes.

In 10 x kT 3{nx + n2)

Dest. Prefix 172.16.1.0/24 192.168.10.10/32 10.10.1.0/30 10.10.3.0/30 10.10.2.0/30 10.10.2.0/30 172.16.2.0/24 192.168.20.20/32 192.168.30.30/32 172.16.1.0/24 192.168.10.10/32 10.10.3.0/30 172.16.2.0/24 192.168.30.30/32 172.16.1.0/24 192.168.10.10/32 10.10.1.0/30 192.168.20.20/32 Next-Hop to Net A system 10.10.1.2 10.10.3.2 10.10.1.2 10.10.3.2 10.10.3.2 10.10.1.2 10.10.3.2 10.10.1.2 10.10.1.2 10.10.1.2 10.10.1.2 10.10.1.2 10.10.3.2 10.10.3.2 10.10.3.2 10.10.3.2 Metric 0 0 0 0 1 1 1 1 1 3 3 3 3 3 3 3 3 3

Here, / is the average distance between two neighbouring doubly ionized monomeric units and e is the effective dielectric constant. For a polyampholyte we have pH = pKlitA - log ocA \-aB aB In 10 x kT dnA 1 SG In 10 x kT

Routing table on R1 (Best routes)

(1.5.23)

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