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where kz,n == n7r fl. If we now integrate equation (2.193) over kz from kz,n - E to kz,n + E and over k~ from kz,n' - E to kz,n' + E, with E being small enough to include only kz,n and kz,n" we obtain



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Polyetherketones and polyethersulfones, also referred to as polyketones and polysulfones, are synthesized by nucleophilic aromatic substitution between aromatic dihalides and bisphenolate salts [Cassidy, 1980; Clagett, 1986; Critchley et al., 1983; Harris and Johnson, 1989; Jayakannan and Ramakrishnan, 2001; Matsumura et al., 2001; May, 1988]. This is shown in Eq. 2-206, where X is halogen and Y is C O or SO2:

(2.194)

2-206

FIAT LUX!





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Although aromatic halides are typically not reactive toward nucleophilic substitution, polymerization is rather facile in these systems because of the electron-withdrawing sulfone and carbonyl groups The bisphenolate salt is formed in situ by the addition of the bisphenol and sodium or other alkali metal carbonate or hydroxide Polysulfones are typically synthesized from aromatic dichlorides in a polar aprotic solvent such as 1-methyl-2-pyrrolidinone (NMP) or dimethyl sulfoxide The polar aprotic solvent increases the nucleophilicity of the phenoxide anion by preferential solvation of cations but not anions Reaction temperatures of 130 160 C are used mainly because of the poor solubility of the diphenolate salt An excess of monohydric phenol or monochloroalkane is used to control the polymer molecular weight A dry reaction system is required for polymerization to yield high-molecular-weight polymer.

So, apart from a normalization factor of vfi/l, the operator Ao: (kz,nz +~) behaves as a continuum annihilation operator in ~ and as a discrete annihilation operator in k z . Then let us we define (2.l95) where

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The presence of water hydrolyzes the phenolate salt, generating sodium hydroxide, which reacts with the aromatic dichloride and alters the stoichiometric ratio of reacting functional groups Polymerization is carried out in the absence of oxygen to prevent oxidation of the bisphenolate Polyketones are typically synthesized from aromatic di uorides in diphenyl sulfone at temperatures of 200 350 C The higher reaction temperatures compared to polysulfone synthesis are needed to keep the polymer from premature precipitation, which would limit the polymer molecular weight There are efforts to use variations on the synthetic scheme to allow lower polymerization temperatures For example, phase-transfer catalysts such as crown ethers or quaternary ammonium salts allow lower reaction temperatures by complexation with the counterion of the phenolate reactant, increasing its nucleophilicity and also its solubility in less polar medium [Hoffman et al, 1994; Sillion, 1999].

[ao:,n(~)' a~, ,n' (~')]

Other reactions have been studied for synthesizing these polymers, including the electrophilic aromatic substitution of acyl and sulfonyl halides on aromatic reactants and the nickelcatalyzed aromatic coupling of aromatic dihalides [Yonezawa et al, 2000] Polymers XL-XLIII are commercially available XL and XLI are referred to as polyetheretherketone (PEEK) and polyetherketone (PEK), respectively XLII and XLIII are known as bisphenol A polysulfone and polyethersulfone, respectively Polymers XLI and XLIII can be synthesized not only using the combination of A and B reactants, but A B also by the self-polymerization of appropriate A reactants B The polysulfones are transparent, amorphous polymers but possess good mechanical properties due to the rigid polymer chains The glass transition temperatures are in the 180 230 C range, and polysulfones are rated for continuous use in the 150 200 C range..

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8(~' - ~)

C(CH3)2

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