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First of all in your case the mergeTiff method should have a Document property, where you pass in the document you create once, because ...

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May 20, 2015 · Convert to Tiff to pdf using itextsharp c# // creation of the document with a certain size and certain margins. iTextSharp.text. // creation of the different writers. // load the tiff image and count the total pages. int total = bm.GetFrameCount(System.Drawing.Imaging. document.Open(); iTextSharp.text.pdf. for (int k = ...

The kp = 2kt 1=2 may vary with [M] because changing [M] may change the viscosity and/or goodness of the solvent (which effect the rates of segmental and/or translational diffusion) An increased dependence of Rp on [M] may also result from the second step (Eq 3-14a) of the initiation sequence becoming the rate-determining step, due to decreased mobility of the primary radicals A lower than 1-order dependence of Rp on [I] may be the indirect result of the correspond2 ing change in polymer molecular weight The termination rate constant would decrease with polymer molecular weight, which in turn decreases with initiator concentration, leading to a dependence of Rp on [I] less than 1-order, even 0-order in some instances.



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One the other hand, 2 the dependence of Rp on [I] becomes close to rst-order in some heterogeneous polymerizations because the propagating radicals become so coiled up and inaccessible as to be incapable of undergoing termination under the usual reaction conditions [Ueda et al, 1984] Termination becomes rst-order in radical concentration The presence of buried or trapped nonterminated radicals has been shown by ESR and the ability of photochemically produced reaction mixtures to continue polymerizing for days after the discontinuation of illumination [Sato et al, 1984] Such long-lived radicals have been studied as a means of producing block copolymers [Sato et al, 1983; Seymour and Stahl, 1977] Thus, vinyl acetate has been polymerized in a poor and/or viscous solvent to produce occluded macroradicals, which then initiate the polymerization of methyl methacrylate, acrylic acid, acrylonitrile, styrene, and N-vinylpyrrolidinone to produce various block copolymers.

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Under conditions where bimolecular termination between propagating radicals becomes dif cult because of the increased viscosity or heterogeneity, primary termination may become important or even the only mode of termination The latter leads to Rp being second-order in [M] and zero-order in [I]..

+ f.L2 At A} .

3-10f Other Accelerative Phenomena Various other rate and molecular weight accelerations have been observed The polymerizations of acrylonitrile, N-vinylpyrrolidinone, and acrylic acid are faster in the presence of water or hydrogen-bonding solvents even though the reaction medium becomes homogeneous instead of heterogeneous as in nonpolar solvents [Burillo et al, 1980; Chapiro and Dulieu, 1977; Laborie, 1977; Olive and Olive, 1978; Senogles and Thomas, 1978] The rate acceleration is due to an increase in the propagation step The effect is very large in some cases; for example, kp for acrylonitrile at 25 C is 2:8 104 L mol 1 s 1 in water compared to 400 L mol 1 s 1 in dimethylformamide.

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Water simultaneously hydrogen-bonds with both monomer and the propagating radical chain end (through the CN group) to increase the effective local monomer concentration at the radical site and also to increase the reactivity of the monomer and/or radical by a polar effect This effect of water has been referred to as a template effect (This template effect is different from that discussed in Sec 3-10d-2) An alternate mechanism proposes that the solvent binds monomer molecules into linear aggregates, which undergo faster propagation due to a favorable orientation (referred to as zip propagation) This autoacceleration sometimes occurs only after some polymer has formed, the formed polymer assisting in stabilizing the linear monomer aggregates (similar to template polymerization) Carboxylic acid monomers such as acrylic and methacrylic acids and trans-butadiene-1carboxylic acid have lower polymerization rates in good solvents and/or at higher pH where monomer exists in ionized form.

32Negative-energy solutions need to be rewritten as positive-energy antiparticles before their energy can be compared to the field energy. When this is done, we find that the expectation value of their energy coincides with the field energy, as it should.

Repulsions between the carboxylate anion groups of the propagating chain end and monomer result in lowered reactivity in the propagation step [Bando and Minoura, 1976; Ponratnam and Kapur, 1977] Monomers containing b-diketone and b-ketoester groups (eg, ethyl 4-methyl-3-oxo-4-pentenoate) exhibit higher reaction rates in benzene compared to acetonitrile The enol tautomer, more plentiful in the less polar solvent, is more reactive than the keto tautomer [Masuda et al, 1987, 1989] The addition of Lewis acids such as ZnCl2 and AlCl3 often increases the polymerization rate of monomers with electron-withdrawing substituents, such as acrylamide, methyl methacrylate, and acrylonitrile [Gromov et al, 1980a,b; Haeringer and Reiss, 1978; Kabanov, 1987; Liaw and Chung, 1983; Madruga and Sanroman, 1981; Maekawa et al, 1978; Sugiyama and Lee, 1977] The mechanism of acceleration is not well established In some instances the metal salt increases the initiation rate by complexing with the initiator.

As J d3 r{Ft F + /12 AtA} is the four-momentum of the field, it is clear that the expectation value of the energy & must be given by

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