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22 of [2061 shows how cavities can be seen as the high-frequencycounterparts of ordinary electronic lumped-circuit oscillators (eg, LC oscillators) For a detailed calculation of perfect cavity modes, see Appendix A and also 2 of Haus's book [276] The formal analogy between Poisson brackets and commutators can also be used to do calculations in classical electrodynamics very similar to the way they are done in quantum electrodynamics (ie, with mode expansions and using the harmonic oscillator Poisson brackets satisfied by the expansion coefficients) This field oscillator approach is described and applied in [90, 233]..

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If you have trouble following the various manipulations of vector expressions involving \l in Section 2.2 and in Appendix A, have a look at Appendix E.





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Although appropriate chemical reactions do not exist to detect the occurrence of head-tohead propagation in all but a few polymers, the use of high-resolution nuclear magnetic resonance spectroscopy (including 1H, 13C, and F19) has greatly increased our knowledge in this area [Bovey and Mirau, 1996; Bovey et al., 1977]. It is now clear that H T propagation is the predominant (>98 99%) mode of propagation in chain polymerization. For some polymers such as polystyrene there is no detectable H H placement (Hensley et al., 1995]. The only exceptions occur when the substituents on the double bond are small (and do not offer appreciable steric hindrance to the approaching radical) and do not have a signi cant resonancestabilizing effect, speci cally when uorine is the substituent. Thus, the extents of H H placements in poly(vinyl uoride), poly(vinylidene uoride), poly(tri uoroethylene), and poly(chlorotri uoroethylene) are about 10, 5, 12, and 2%, respectively [Cais and Kometani, 1984, 1988; Guiot et al., 2002; Ovenall and Uschold, 1991]. The effect of increasing the polymerization temperature is an increase in the extent of H-H placement, but the effect is small. Thus the H-H content in poly(vinyl acetate) increases from 1 to 2% when the temperature is increased from 40 to 100 C; the increase is from 10 to 14% for poly(tri uoroethylene) when the temperature is increased from 80 to 80 C. 3-2c Synthesis of Head-to-Head Polymers

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Milonni's book [451] offers a quite comprehensive pedagogical account of the Casimir effect, including a discussion of the curious model that Casimir proposed for the electron. Most of the important literature on the Casimir force is listed in [377], with key advances discussed in detail in the recent review [66]. For a recent measurement of the Casimir force, see [97]. For a calculation of the fluctuations around the expected value of the Casimir force (i.e., variances), see the chapter by Barton in [49] . For more on the vacuum catastrophe, see [5, 316, 483, 511, 629].

Some polymers consisting entirely of head-to-head placements have been deliberately synthesized to determine if signi cant property differences exist compared to the head-totail polymers. The synthetic approach involves an appropriate choice of monomer for the particular H H polymer. For example, H H poly(vinyl chloride) is obtained by chlorination of 1,4-poly-1,3-butadiene,

2.1 Do the Fourier integral (2.66) using (2.67) with the approximation (2.69). This integral is wellsuited for contour integration. Note that for t - t' < 0, the contour must be closed on the lower half of the complex plane not to get any contribution from the semicircle arch when its radius is made infinitely large. The converse holds for t - t' > o. 2.2 Calculate how the pendulum oscillates with the driving force given by (2.71), which is switched on at t = 0 and off at t = T. Use the Green's function method (2.64), with the approximate Green's function (2.70). 2.3 Show that the solution of (2.75) with the driving force F t) = Aexp(d) sinwt is given by (2.79). Start from equation (2.77) and note that its solution is simply

concentration ($10 6 mol L 1 ) During the dark period that follows the pulse most of the primary radicals form propagating radicals, which then propagate, but some primary radicals terminate by coupling Normal coupling and disproportionation occur during the dark period, but a large fraction of propagating chain do not terminate because the cycle time is short The second laser pulse again produces a burst of primary radicals Most surviving propagating chains from the dark period between the rst and second laser pulses are almost instantaneously terminated by the high concentration of primary radicals formed in the second laser pulse But some of the propagating chains survive and continue to propagate during the second dark period.

Y (k t)

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