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and b-scission of the polyester to form acid and alkene end groups that subsequently react to form an anhydride plus acetaldehyde



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138 B J Dalton and B M Garraway Non-Markovian decay of a three-level cascade atom in a structured reservoir Physical Review A, 68(3):033809, September 2003 139 B J Dalton and P L Knight The standard model in cavity quantum electrodynamics: I General features of mode functions for a Fabry-Perot cavity Journal of Modern Optics, 46(13): 1817-1837, November 10,1999 140 B J Dalton and P L Knight The standard model in cavity quantum electrodynamics: II Coupling constants and atom field interaction Journal of Modern Optics, 46(13):1839-1868, November 10,1999 141 D A R Dalvit and P A Maia Neto Decoherence via the dynamical Casimir effect Physical Review Letters, 84(5):798-801, January 31, 2000 142 A Das Gupta Disentanglement formulas: An alternative derivation and some applications to squeezed coherent states American Journal of Physics, 64(11): 1422-1427, November 1996 143 K Datta.

2-124





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Other reported side reactions include dehydration between alcohol end groups, decarboxylatio of diacid monomer, dehydration between carboxyl end groups, and scission and polymerization of the alkene end groups formed in Eq 2-124 Side reactions directly interfere with the polymerization by altering the stoichiometric ratio of the reacting functional groups, and this affects the polymer molecular weight Additionally, side reactions can have deleterious effects on polymer properties For example, diethylene glycol formed by dehydration of ethylene glycol (Eq 2-123) takes part in the polymerization For poly (ethylene terephthalate), the Tm is decreased by the introduction of diethylene glycol units in place of ethylene glycol units in the polymer chain The presence of acetaldehyde as an impurity causes problems when poly(ethylene terephthalate) is used to produce food and beverage containers Acetaldehyde also results in discoloration in the nal polymer product, due to the formation of aldol-type by-products.

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The quantum Poisson bracket and transformation theory in quantum mechanics: Dirac's early work in quantum theory Resonance, 8(8):75-85, August 2003 Online at http://wwwiasacinlresonancelAugust2003/August2003Contentshtml 144 L Davidovich On the Weisskopf-Wigner approximation in atomic physics PhD dissertation University of Rochester, Rochester, NY, 1975 145 W R Davies, M T Chu, P Dolan, J R McConnell, L K Norris, E Ortiz, R J Plemmons, D Ridgeway, B K P Scaife, W J Stewart, J W York Jr, W O Doggett, B M Gellai, A A Gsponer, and C A Prioli, editors Cornelius Lanczos: Collected Published Papers with Commentaries North Carolina State University, Raleigh, NC, 1998 146 C A Deavours The quaternion calculus American Mathematical Monthly, 80(9):995-1008, November 1973 147 V DeGiorgio and M O Scully Analogy between the laser threshold region and a second-order phase transition Physical Review A, 2(4): 1170-1177, October 1970 148 S R.

The production of food-grade polymers requires the use of purer reactants than those to be used for applications in which the polymers do not contact foodstuffs The carboxyl functional groups for synthesizing polyesters can be supplied by using diacids, acid anhydrides, diacid chlorides, or dimethyl esters The cost and purity of the different reactants is important as are the reaction conditions required Direct reactions of diacids or anhydrides with diols are often avoided because of the high temperatures required to completely aliminate water However, these reactions are used to produce low-molecular-weight and crosslinked polyesters based on phthalic and maleic anhydrides (Sec 2-12a) Diacid chlorides have been used with dihydric phenols to produce polycarbonates (Sec 2-8e).

DeGroot and J Vlieger Derivation of Maxwell's equations: The statistical theory of the macroscopic equations Physica, 31:254-268, 1965 149 R P Dellavalle, E J Hester, L F Heilig, A L Drake, J W Kuntzman, M Graber, and L M Schilling Going, going, gone: Lost Internet references Science, 302:787-788, October 31, 2003 150 H H Denman On linear friction in Lagrange's equation American Journal of Physics, 34(12):1147-1149,1966..

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