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Past the gel point the value of X w =X n for the sol fraction decreases Finally, at a p 1, the whole system has been converted to gel (ie, one giant molecule) and X w =X n equals 1 As mentioned previously, the behavior of systems containing bifunctional as well as trifunctional reactants is also governed by the equations developed above The variation of wx for the polymerization of bifunctional monomers, where the branching coef cient a is varied by using appropriate amounts of a trifunctional monomer, is similar to that observed for the polymerization of trifunctional reactants alone The distribution broadens with increasing extent of reaction The effect of unequal reactivity of functional groups and intramolecular.



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569. R. E. Slusher, L. W. Hollberg, B. Yurke, J. C. Mertz, andJ. F. Valley. Observation of squeezed states generated by four-wave mixing in an optical cavity. Physical Review Letters, 55(22):2409-2412, November 25, 1985. 570. T. H. Solomon and S. Fallieros. Relativistic one-dimensional binding and twodimensional motion. Journal of the Franklin Institute, 320:323-344,1985. 571. A. Sommerfeld. Partial Differential Equations in Physics. Academic Press, New York, 1949. Online at http://mpec.sc.mahidol.ac.thlphysmathl. 572. G. Spavieri. Classical Lagrangian and quantum phase of the dipole. Physics Letters A, 310(1): 13-18, April 7, 2003. 573. M. B. Spencer and W. E. Lamb Jr. Laser with a transmitting window. Physical Review A, 5(2):884-892, February 1972. 574. C. M. Sprenkle. Warrant prices as indicators of expectations and preferences. Yale Economic Essays, 1(2):179-232, 1961. Reprinted in [122], pp. 412-474. 575. L. Spruch. Pedagogic notes on Thomas-Fermi theory (and on some improvements): Atoms, stars, and the stability of bulk matter. Reviews ofModern Physics, 63(1):151-209, January 1991. 576. G. Squires. J. J. Thomson and the discovery of the electron. Physics World, 10(4), April 1997. 577. P. Stehle. Atomic radiation in a cavity. Physical Review A, 2(1): 102-106, July 1970. 578. A. M. Steinberg, P. G. Kwiat, and R. Y. Chiao. Dispersion cancellation in a measurement of the single-photon propagation velocity in glass. Physical Review Letters, 68(16):2421-2424,ApriI20, 1992. 579. A. M. Steinberg, P. G. Kwiat, and R. Y. Chiao. Dispersion cancellation and highresolution time measurements in a fourth-order optical interferometer. Physical Review A, 45(9):6659-6665, May 1, 1992.





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Fig. 2-19 Number- and weight-average degrees of polymerization a function of a for a trifunctional as polymerization. The portions of the plots after the gel point a 1 are for the sol fraction only. After 2 Flory [1946] (by permission of American Chemical Society, Washington, DC).

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580 R L Stratonovich Topics in the Theory of Random Noise, volumes I and II Gordon & Breach, New York, 1963 581 E C G Stiickelberg La mecanique du point materiel en tMorie de relativite et en tMorie des quanta Helvetica Physica Acta, 15:23-37, 1942 582 C Stuckens and D H Kobe Quantization of a particle with a force quadractic in the velocity Physical Review A, 34(5):3565-3567, November 1986 583 E C G Sudarshan ,Equivalence of semiclassical and quantum mechanical descriptions of statistical light beams Physical Review Letters, 10(7):277-279, April 1, 1963 584 A Sudbery Quaternionic analysis Mathematical Proceedings of the Cambridge Philosophical Society 85: 199-225, 1979 585 B Sutherland and D C Mattis Ambiguities with the relativistic a-function potential Physical Review A, 24(3):1194-1197, September 1981 586 O SveIto Principles of Lasers Plenum Press, New York, 1989 Translated from the Italian original Pricipi dei laser by D C Hanna 587.

cyclization is to broaden the molecular weight distribution [Case, 1957; Macosko and Miller, 1976; Miller and Macosko, 1980; Muller and Burchard, 1978].

K R Symon Mechanics Addison-Wesley,Menlo Park, CA, 3rdedition, 1971 588 P G Tail Quaternions In Encyclopredia Britannica, volume Xx, pp 160-164 9th edition, 1886 Online at http://homepipelinecomrhbakerIlquaternion/ 589 S M Tan A computational toolbox for quantum and atomic optics Journal of Optics B, 1(4):424-432, August 1999 590 W G Teich and G Mahler Stochastic dynamics of individual quantum systems: Stationary rate equations Physical Review A, 45(5):3300-3318, March 1, 1992 591 D ter Haar, editor The Old Quantum Theory Pergamon Press, Oxford, 1967 Selected readings in physics 592 R J Thompson, G Rempe, and H J Kimble Observation of normal-mode splitting for an atom in an optical cavity Physical Review Letters, 68(8):11321135, February, 24 1992 593 S P Thompson Calculus Made Easy The Macmillan, London, 3rd edition, 1983 First published in 1910 594 J 1 Thomson.

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