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The rst few atoms of the two polymer chain segments attached to C* are the same and such stereocenters do not contribute measurably to the optical activity of the polymer The only stereocenters with signi cant optical activity are those at the ends of the polymer chain, but their population is negligible for a high-molecular-weight polymer The sum of contributions from all the stereocenters is such that optical activity is below the limits of detection (This discussion of optical activity excludes optical activity arising from the existence of a polymer molecule exclusively in a chiral conformation, a very rare occurrence except for biological macromolecules; see Sec 8-8b A typical polymer in solution exists in the random-coil conformation Many of the conformations are chiral, but on a time-average basis there are equal numbers of conformations of opposite rotation and the net rotation is zero.



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dX(t) = {A (X(t), t)

) Thus, it is more useful to classify stereocenters such as those in Ia and Ib as achirotopic The terms stereocenter, chirotopic, and achirotopic will be used in this text in line with the most recent terminology However, other terms are found in the older literature C* was previously referred to as a chiral or pseudochiral center The term pseudochiral center is based on the same convention used to classify C* as achirotopic instead of chirotopic The terms asymmetric and pseudoasymmetric center are found in much older literature 8-1a-2 Tacticity.

+ ~B (X(t), t)





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The regularity in the con gurations of successive stereocenters determines the overall order (tacticity) of the polymer chain. If the R groups on successive stereocenters are randomly distributed on the two sides of the planar zigzag polymer chain, the polymer does not have order and is termed atactic. Two types of ordered or tactic structures or placements can occur: isotactic and syndiotactic. An isotactic structure occurs when the stereocenter in each repeating unit in the polymer chain has the same con guration. All the R groups will be located on one side of the plane of the carbon carbon polymer chain either all above or all below the plane of the chain. A syndiotactic polymer structure occurs when the con gurations of the stereocenters alternate from one repeating unit to the next with the R groups located alternately on the opposite sides of the plane of the polymer chain. These different polymer structures are shown in Fig. 8-1. The various polymer structures are described by three different pictorial representations. The ones on the far left side of Fig. 8-1 show the polymer chain in the plane of this page with the H and R groups above (triangular bonds) and below (dotted bonds) that plane. The representations in the middle are the corresponding Fischer projections. Verticle lines in the Fischer projections correspond to bonds projecting behind the plane of this page; horizontal lines represent bonds projecting in front of the plane. This is the usual convention for Fischer projections [Bovey, 1982]. The con guration at each carbon atom in the polymer chain is drawn in the Fischer projection by imagining the rotation of each carbon carbon bond in the polymer chain into an eclipsed conformations as opposed to the staggered conformation that actually exists. The

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Convert worksheet to PDF in C#, VB.NET. Step 1: Initialize a new instance of Workbook class and load the sample Excel file. Workbook workbook = new Workbook(); Step 2: Get its first worksheet. Worksheet sheet = workbook.Worksheets[0]; Step 3: Convert the selected worksheet to PDF and save to file. sheet.SaveToPdf( " ...

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(8.65) So Stratonovich's stochastic differential equation (8.63) is equivalent to an Ito stochastic differential equation where the drift coefficient is given by

representations on the far right side of Fig. 8-1, recommended by IUPAC [1981], are obtained by rotating the previous Fischer projections 90 counterclockwise. The resulting Fischer projections do have the advantage of showing the polymer chain going in the same direction as the far-left representations. Their disadvantage is that one must always keep in mind that the usual Fischer convention for horizontal (forward) and vetical (back) bonds is reversed. These rotated Fischer projections will be used in the remainder of this chapter. The Fischer projections show that isotactic placement corresponds to meso or m-placement for a pair of consecutive stereocenters. Syndiotactic placement corresponds to racemo (for racemic) or r-placement for a pair of consecutive stereocenters. The con gurational

A (X(t), t) = A(X{t), t)

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