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8.7 Do the integrals in (8.103) and (8.104). Then, assuming that V limit of t -+ 00 and obtain (8.105).



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Different types of copolymers are possible with regard to sequencing of the two repeating units relative to each other. Thus a copolymer with an overall composition indicated by XXXV could have the alternating copolymer structure shown in XXXV, in which the R, R0 , R00 , and R000 groups alternate in that order over and over again along the polymer chain; or the block copolymer structure XXXVII, in which blocks of one type of homopolymer structure are attached to blocks of another type of homopolymer structure; or the statistical copolymer structure, in which there is an irregular (statistical) distribution of R and R00 groups as well as R0 and R000 groups along the copolymer chain. Similarly, one can have alternating, block, and statistical copolymers for the overall composition XXXVI.





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8.8 Write down the (nl, In) )-matrix element of(8. 119) as a recursion relation and show that the solution is given by (8.121). 8.9 Consider a two-level atom under polarization damping interacting with the radiation field in a single-mode cavity according to (8.124). To focus only on spontaneous emission, take the initial field as the vacuum. Then the total density matrix will be of the form

For the statistical copolymer the distribution may follow different statistical laws, for example, Bernoullian (zero-order Markov), rst- or second-order Markov, depending on the speci c reactants and the method of synthesis. This is discussed further in Secs. 6-2 and 6-5. Many statistical copolymers are produced via Bernoullian processes wherein the various groups are randomly distributed along the copolymer chain; such copolymers are random copolymers. The terminology used in this book is that recommended by IUPAC [Ring et al., 1985]. However, most literature references use the term random copolymer independent of the type of statistical distribution (which seldom is known). The alternating and statistical copolymer structures can be symbolized as

where A and B represent two different repeating units. Different block copolymers are distinguished by the number of blocks per molecule, for example

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+ 10}(110 POI + Il}(010 Pbl'

which are referred to as AB diblock, ABA triblock, ABAB tetrablock, and AB multiblock copolymers, respectively. For the various block copolymers the values of m and p as well

where Pik is an atomic density matrix, 0 stands for the tensor product, 10} is the vacuum, and 11) is the one-photon state. Assuming that the atom is initially in the excited state, solve (8.124) and show that

as n are average values; thus, there is a distribution of block lengths and number of blocks along the copolymer chain. There is considerable structural versatility possible for statistical and block copolymers in terms of the relative amounts of A and B in a copolymer. For block copolymers there is the additional variation possible in the number of blocks of A and B and their block lengths (values of m and p). Alternating, statistical, and random copolymers are named by following the pre x poly with the names of the two repeating units. The speci c type of copolymer is noted by insertng -alt-, -stat-, or -ran- in between the names of the two repeating units; -co- is used when the type of copolymer is not speci ed: poly(A-co-B), poly(A-alt-B, poly(A-stat-B), poly(A-ran-B). Block copolymers are named by inserting -block- in between the names of the homopolymers corresponding to each of the blocks. The di-, tri-, tetra-, and multiblock copolymers are named as polyA-block-polyB, PolyA-block-polyB-block-polyA, polyAblock-polyB-block-polyA-block-polyB, and poly(polyA-block-polyB), respectively. Adoption in the literature of some of these IUPAC recommendations for naming copolymers has been slow.

Cavity Quantum Electrodynamics: The Strange Theory of Light in a Box Sergio M. Dutra Copyright 2005 John Wiley & Sons, Inc.

A fourth type of copolymer is the graft copolymer in which one or more blocks of homopolymer B are grafted as branches onto a main chain of homopolymer A. Graft copolymers are named by insertng -graft- in between the names of the corresponding homopolymers; the main chain is named rst (e.g., polyA-graft-polyB). Graft copolymers are relatively unimportant for step polymerizations because of dif culties in synthesis. Graft copolymers are considered further in Sec. 9-8. The discussion to this point has involved copolymers in which both repeating units have the same functional group. A second catagory of copolymer involves different functional groups in the two repeat units, for example, an amide ester copolymer such as

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