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1. R COX 2. HBr 3. Heat ( CO2)

Now if ab > 0, the two limits of the integral on the right-hand side of (E24) will be either both 00 or both -00 in the limit of -y -+ 00, making the integral vanish. But if ab < 0, the lower limit will become -00 and the upper 00 when -y -+ 00. Moreover, f(~h) will become f(O) as -y -+ 00, so that we can write



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manner, one can favor various intramolecular cyclization reactions of supported diesters, cyanoesters, and dinitriles, as well as the cyclization reaction of a supported malonic ester with an a,o-dihalide [Crowley et al., 1973; Mohanraj and Ford, 1985; Patchornik and Kraus, 1970]. 4. Other applications of the polymer substrate technique include the synthesis of threaded macrocyclic systems (hooplanes, catenanes, knots), the retrieval of a minor component from a reaction system, and the trapping of reaction intermediates [Frechet, 1980a,b; Hodge, 1988; Hodge and Sherrington, 1980; Mathur et al., 1980]. REFERENCES

dx f(x) .,l.:.~ -y g(-yx) =





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Adibi, K., M. H. George, and J. A. Barrie, Polymer, 20, 483 (1979); J. Polym. Sci. Polym. Chem. Ed., 19, 57 (1981). Akelah, A. and D. C. Sherrington, Polymer, 24, 1369 (1983). Alexandratos, S. D. and D. H. J. Miller, Macromolecules, 33, 2011 (2000). Alexandratos, S. D. and S. Natesan, Eur. Polym. J., 35, 431 (1999). Alfrey, T., Jr., H. C. Haas, and C. W. Lewis, J. Am. Chem. Soc., 73, 2851 (1951). Allen, G and J. C. Bevington, eds., Polymer Reactions, Vol. 6 in Comprehensive Polymer Science, Pergamon Press, New York, 1990.

(E25)

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Allen, P W, Natural Rubber and the Synthetics, Crosby Lockwood, London, 1972 Alliger, G and I J Sjothun, eds, Vulcanization of Elastomers, Van Nostrand Reinhold, New York, 1964 Andrews, G D and R L Dawson, Chlorosulfonated Polyethylene, pp 513 522 in Encyclopedia of Polymer Science and Engineering, 2nd ed, Vol 6, H F Mark, N M Bikales, C G Overberger, and G Menges, eds, Wiley-Interscience, New York, 1986 Arshady, R, G W Kenner, and A Ledwith, Makromol Chem, 177, 2911 (1976) Arthur, J C, Jr, Chemical Modi cation of Cellulose and its Derivatives, Chap 2 in Comprehensive Polymer Science, Vol 6, G C Eastmond, A Ledwith, S Russo, and P Sigwalt, eds, Pergamon Press, Oxford, 1989 Asami, R, M Takaki, K Kyuda, and E Asakura, Polymer J, 15, 139 (1983) Bao, Y T and C G Pitt, J Polym.

This is just another way of writing the basic property (El) of the delta function. So it justifies (E21). As we mentioned before, we delay to Section E3 any considerations about what happens when ab = O. Aguirregabiria and collaborators [8] show how (E21) can be used to obtain a "quick and dirty" derivation of the identities (E16) and (E17), which is much simpler and shorter than Frahm's original derivation [222]. But rather than presenting this derivation, we will now reproduce their derivation of a much lesser known identity involving delta functions which was first obtained by Aichelburg and Sexl [11] in the context of general relativity. First note that if a = lim,,(-+oo h( -y), then lim -y 9 ({x - h(-y)}-y)

Sci Polym Chem Ed, 28, 741 (1990) Barany, G, N Kneib-Cordonier, and N G Mullen, Polypeptide Synthesis, pp 811 858 in Encyclopedia of Polymer Science and Engineering, 2nd ed, Vol 12, H F Mark, N M Bikales, C G Overberger, and G Menges, eds, Wiley-Interscience, New York, 1988 Barth, V and E Klesper, Polymer, 17, 777, 787, 893 (1976) Bateman, L, The Chemistry and Physics of Rubber-Like Substances, Wiley-Interscience, New York, 1963 Battaerd, H A and G W Tregear, Graft Copolymers, Wiley-Interscience, New York, 1967 Benham, J L and J F Kinstle, Chemical Reactions on Polymers, Am Chem Soc Symp Ser, Vol 364, American Chemical Society, Washington, DC, 1988 Beresniewicz, A, J Polym Sci, 39, 63 (1959) Bergbreiter, D E, J Polym Sci Polym Chem Ed, 39, 2351 (2001); Chem Rev, 102, 3345 (2002) Bikales, N M and L.

= g o(x - a).

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