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Convert Excel file to PDF in C# and VB.NET. GemBox.Spreadsheet enables you to easily convert an Excel file to different file formats in C# and VB.NET. For example, you can convert Excel file to a different spreadsheet format (XLSX, XLS, ODS, CSV, or HTML) or to PDF, XPS, and image formats.

Note: To view the field again, right-click the field next to the hidden field, click Unhide Fields, select the column and click OK.

(8.39)

polymerizations. However, the effect is relatively small as the extent of disproportionation in these two polymerizations is no greater than 10% at most [Bamford et al., 1969a,b].



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Steps to convert excel document to PDF program matically:
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In other words, F is a very special force: it fluctuates so much that it is only instantaneously correlated to itself. This is all that we need for introducing noise in our simple laser model. If, however. you wish to know a bit more about Langevin equations, read the next subsection.

In many polymerization systems the polymer molecular weight is observed to be lower than predicted on the basis of the experimentally observed extents of termination by coupling and disproportionation. This effect is due to the premature termination of a growing polymer by the transfer of a hydrogen or other atom or species to it from some compound present in the system the monomer, initiator, or solvent, as the case may be. These radical displacement reactions are termed chain-transfer reactions and may be depicted as





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SIn fact. the probability p(x, t) can also be viewed as a conditional probability of finding the particle at x at time t given that it started at the origin at time O. To see this. just take x, = 0 and t' = 0 in (8.35) and compare with (8.31).

3-102

Langevin's equation was the first example of what mathematicians now call a stochastic differential equation. As it stands, however, (8.29) can lead to ambiguities. Let us try, for example, to derive Langevin's assumption that (x(t)F(t ) vanishes using only (8.29), and (8.39). Integrating (8.29), and taking x(O) = 0, we can write

where XA may be monomer, initiator, solvent, or other substance and X is the atom or species transferred. Chain transfer to initiator was referred to earlier as induced initiator decomposition (Sec. 3-4g-1). The rate of a chain-transfer reaction is given by

Rtr ktr M XA 3-103

(x(t)F(t ) =

where ktr is the chain-transfer rate constant. Chain transfer results in the production of a new radical A , which then reinitiates polymerization

lot dt' (F(t)F(t' ). lot dt' 8(t - t').

3-104

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One way to enter data into your database is to type it directly into an Access table. Alternatively, you can create a form based on your table to simplify data entry. Forms present your table fields in an easy-to-read, fill-in-the-blank format. When you create a form based on a table, Access inserts a field into the form for each field in the table. Forms, which enable you to enter records one at a time, are a great way to speed up data entry, particularly if other users are adding information to your database list.

(8.40)

Chain transfer is a chain-breaking reaction; it results in a decrease in the size of the propagating polymer chain. The effect of chain transfer on the polymerization rate is dependent on whether the rate of reinitiation is comparable to that of the original propagating radical. Table 3-3 shows the four main possible situations that may be encountered. Reinitiation is rapid in cases 1 and 2, and one observes no change in the polymerization rate. The same number of monomer molecules are consumed per unit time with the formation of larger numbers of smaller-sized polymer molecules. The relative decrease in X n depends on the magnitude of the transfer constant. When the transfer rate constant ktr is much larger than that for propagation (case 2) the result is a very small-sized polymer (X n 1 5) referred to as a

(8.41)

TABLE 3-3 Effect of Chain Transfer on Rp and X n Relative Rate Constants for Transfer, Propagation, and Reinitiation kp kp kp kp ) ktr ( ktr ) ktr ( ktr ka ka ka ka kp kp < kp < kp

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