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+ 1/v = ( ix+fl--)1/v, (1.1.11) Y = ( r : r - ) The numerical values of the activity coefficients yx, ym and yc (and also of the activities ax, am and ac) are different (for the recalculation formulae see Appendix A). Obviously, for the limiting case (for a very dilute solution) a



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configuration for a home network, and it provided home users with basic Internetrelated services. In contrast, more modern home networks such as the one shown in Figure 6.3 support multiple services, and these services can be delivered on a single technology by a single or multiple providers. Home networks have evolved from a simple PC connected to a modem or a switch to multiple PCs, home televisions, and digital phones all connected via a single L2 technology to a home router that is managed at the home by the user and not by the provider. The router on one side of the network connection connects to the home network and on the other side connects to the service provider access device. The demarcation point in this case is the modem in Figure 6.3.





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y ,* = y ,m = y .c i (1.1.12) The activity coefficient of the solvent remains close to unity up to quite high electrolyte concentrations; e.g. the activity coefficient for water in an aqueous solution of 2 M KC1 at 25 C equals y0>x = 1.004, while the value for potassium chloride in this solution is y >x = 0.614, indicating a quite large deviation from the ideal behaviour. Thus, the activity coefficient of the solvent is not a suitable characteristic of the real behaviour of solutions of electrolytes. If the deviation from ideal behaviour is to be expressed in terms of quantities connected with the solvent, then the osmotic coefficient is employed. The osmotic pressure of the system is denoted as JZ and the hypothetical osmotic pressure of a solution with the same composition that would behave ideally as JT*. The equations for the osmotic pressures JZ and JZ* are obtained from the equilibrium condition of the pure solvent and of the solution. Under equilibrium conditions the chemical potential of the pure solvent, which is equal to the standard chemical potential at the pressure / , is equal to the chemical potential of the solvent in the solution under the osmotic pressure JZ, li%(T, p) = iio(T, p + JZ) = iil(Ty p + jz) + RT\n a0 (1.1.13) where a0 is the activity of the solvent (the activity of the pure solvent is unity). As approximately

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Composition is the plan, placement, or arrangement of the elements in a photograph to produce the photographer s desired effect. The general goal is to select and place the appropriate elements within the scene in order to communicate your ideas and feelings with the viewer on an emotional level to produce a desired response.

Figure 6.3 A modern home network that supports advanced user services such as IP telephony, Video on Demand (VoD), and interactive gaming over a high-speed Digital Subscriber Link (DSL) or cable Internet.

p + Jt)- l* o(T, p) = VOJZ (1.1.14)

The data for all the services (in this single-provider, multiple-services scenario) is sent to the modem via DSL or cable technology. every device in the home in this scenario requires an IP address to be able to connect to the Internet. There are several disadvantages to this configuration. First, it is not financially viable to have a unique public IP-routed address for every device in a home network. On top of this, it would not be a scalable solution. For the traffic to be received back to each device, the ISP would have to keep track of every home device for a single access point, and an ISP is typically not interested in maintaining multiple IP addresses for the average home user.

we obtain for the osmotic pressure JZ= \na0 (1.1.15)

The best and most scalable solution is to have a home-managed router that assigns private IP addresses to each of the home devices and has a public IP address representing the home toward the ISP. Recall that private IP addresses are addresses that can be used by anyone for their own private networks, but that are not routable on the Internet. This makes them an ideal solution for large numbers of home networks that need to talk to each other on their local network, but that can all use a single (or sometimes multiple) public address to communicate with devices on the Internet. This magic is made possible by using network Address Translation (nAT) or Port Address Translation (PAT). Let s examine how this process works.

where v0 is the molar volume of the solvent. For a dilute solution In a0 = In x0 = In (1 - E *,-) ~ - E xt Mo E mh giving for the ideal osmotic

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