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In contrast to X-ray diffraction, the LEED method yields information only on the twodimensional surface structure The LEED method is used to study clean surfaces and substances adsorbed on crystalline surfaces An interesting structural change ('surface reconstruction') is often observed after contact of the electrode with the electrolyte A disadvantage of the LEED method compared to X-ray diffraction is the necessity of working ex situ The electrochemistry of modified electrodes occasionally employs a rather special method of electron spectroscopy inelastic electron tunnelling spectroscopy (IETS) based on precise measurement of the electrical conductivity of an electrode covered with an oxide layer and possibly with other adsorbed substances, in dependence on the voltage The electrons 'see' the layer of oxide or adsorbed molecules as a potential barrier that can be overcome by tunnelling.



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At a definite potential, a characteristic change in the conductivity is observed, resulting from non-elastic interaction of the tunnelling electrons with the vibrational levels in the studied layer of oxide or adsorbates on the electrode The IETS method thus yields analogous data to those obtained from the other vibrational spectroscopic methods The non-elastic tunnelling phenomenon is not limited by the selection rules of vibrational spectroscopy and thus bands can be observed that are active in both the Raman and infrared spectra The IETS method has an advantage in its ability to study very thin surface layers on the electrodes and, last but not least, in the quite simple instrumentation (eg it is not necessary to work in a vacuum) Measurements can be carried out, however, only ex situ and on a limited number of materials The aluminium oxide-covered electrode is most advantageous.

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10a. Can the export policy be assigned only to a particular area Try issuing the export command within the context config router ospf area 0. 11. Confirm using ping, and optionally traceroute, that each router can reach every interface configured in OSPF on every other router, including loopbacks. If any interface isn t reachable, double-check that you have correctly configured that interface into OSPF and that the router is designated as asbr. 12. Use a show command to display the routing table on each router. Compare the result with the routing tables you obtained in Exercise 8.2. Verify the Protocol column to ensure that none of the routes is static.

As mentioned above, the methods based on detection of electrons or ions or probing the electrode surface by these particles are generally handicapped by the necessity to move the studied electrode into vacuum, ie to work ex-situ There are, however, two important exceptions to this rule: electrochemical mass spectrometry and electrochemical scanning tunnelling microscopy..

*B:PE1# show router route-table =============================================================== Route Table (Router: Base) =============================================================== Dest Prefix Type Proto Age Pref Next Hop[Interface Name] Metric --------------------------------------------------------------140.10.0.1/32 Local Local 03d02h27m 0 system 0 140.10.0.3/32 Remote OSPF 02h16m53s 10 140.10.0.102 100 140.10.0.11/32 Local Local 03d01h09m 0 loopbackTest 0 140.10.0.12/32 Remote OSPF 00h09m57s 150 140.10.0.102 1 140.10.0.96/30 Local Local 03d02h01m 0 toPE2 0 140.10.0.100/30 Local Local 03d01h45m 0 toCE1 0 150.10.0.1/32 Remote OSPF 02h16m39s 10 140.10.0.98 100 150.10.0.11/32 Remote OSPF 00h09m45s 150 140.10.0.98 1

Electrochemical mass spectrometry was recently introduced for direct study of the products of electrochemical processes For this purpose, an electrochemical cell is connected to the vacuum chamber of a mass spectrometer by a porous Teflon membrane This membrane is at the electrolyte side covered by a layer of porous platinum serving as a working electrode When the pore size is suitably selected, the solvent molecules do not pass through the hydrophobic Teflon membrane, but some molecules generated at the platinum electrode (eg H2, O2, NO, NO2, CO2) can penetrate through the membrane, and are subsequently detected by the mass spectrometer The analytical response is rather fast, typically < 05 s, which allows the measurement of mass-potential curves in parallel with usual current-potential diagrams.

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According to the used potential regime, we can distinguish the mass spectrometric cyclic voltammetry, MSCV (with triangular potential changes) or differential electrochemical mass spectrometryp, DEMS (with square-wave potential changes) The electrochemical mass spectrometry seems promising, especially for the study of anodic oxidation of organic substances For instance, the detection of CO2 during anodic oxidation of propylene carbonate is a suitable complementary method to SNIFTIRS (see the example discussed on page 334) Electrochemical scanning tunnelling microscopy (ESTM) has recently been recognized as a powerful technique for in-situ characterization of the topography of electrode surfaces extending to the atomic level This method was originally developed for the study of conducting surfaces in vacuum, but is readily applicable also to surfaces in gaseous or liquid environment The latter application was first demonstrated in 1986 on graphite in aqueous solutions.

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