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x direction to facilitate comparison with the familiar results. For this case, the displacement radius vector is r 0:3 and the displacement angle is y p rad. The last two rows show the results for the general vectorial displacements of r 0:632 and the displacement angle y 0:322 rad (the third row), and r 0:361 and the displacement angle y 5:695 rad (the fourth row). The center of the sheared wavefront is translated by the magnitude of the displacement radius vector r along the direction y with respect to the origin at the center of the square pupil. We discuss each gure in more detail. Figure 4.54 shows the simulated interferometric patterns when 4 waves of defocus and no defocus are added to 2.5 waves of spherical aberration. The second row presenting the intensity patterns of lateral shearing interferometer is in agreement with the patterns presented at the beginning of this chapter. It con rms the general reliability of our simulations. The fringe patterns outside focus appear as





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different for each one of two orthogonal lateral shears. Then, if the defocusing is referred to the point in the middle between the compensators, the expression for the fringe pattern becomes @W d @W d x S y T nl: 4:36 @x 2R2 @y 2R2 In this case, the fringes for spherical aberration become S-shaped, similar to those displayed in Figure 4.7. A polarization phase shifter incorporating a birefringent plane parallel plate may be used to measure an aspherical surface. Weijers et al. (1998) present a simple calculation for ray propagation through uniaxial, birefringent element. Its inherent aberrations are derived. The method is used to record directly phase-shifted interferograms as needed for the interferogram evaluation and phase reconstruction. Begbie et al. (2001) performed a rigorous analysis using Mueller matrices to evaluate the state of polarization necessary to eliminate fringe ambiguity.

Figure 5.3. Experimentally measured re ectivity and delity versus input energy using a 90atm N2 SBS cell. The measurements were made for (a) the full quasi-Gaussian temporal pro le and (b) the fast-rise-time truncated temporal pro le.

A device is necessary to obtain VPaK conditions inside the reaction vessel. The parameter must change homogeneously and coherently with the modulating function and without altering any other factors important for the reaction or its analytical monitoring. The parameter can change in a vessel being part of the analytical instrument, for example, an ultraviolet visible (UV Vis) spectrophotometric cell [39, 41, 45, 14, 47, 48], an infrared (IR) cell [42, 46], or a uorometer cell [45, 51], or a polarimetric tube [27, 49]. It can change in a reactor vessel where the analytical signal can be read in some way, for example using an optical ber cell for spectrophotometry [52 54] or a conductometric cell [16, 34, 40]. Another possibility is to transport the solution from the reaction vessel to the analytical instrument by a peristaltic pump [38]. When altenative ways are not practicable, samples can be taken at suitable time intervals and analyzed apart [29, 31, 35, 39, 43, 50]. Any system satisfying the conditions cited above can be useful as VPaK devices. For VTK programmable thermostatic baths (with the possibility of external circulation) and temperature programmers using the Peltier effect are very convenient. It is always necessary to homogenize the temperature and the composition of the solution with good stirring, monitoring the temperature by measuring it inside the reaction vessel, possibly memorizing it in a computer. A linear increasing temperature is suf cient and it is enough easy to realize, but other modulating functions, for various reasons, have been tested [33, 35, 47]. However, for future particular applications, the use of a computer with suitable software can easily generate T(t) pro les having various shapes.

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