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Auburn, R.P., Kreil, D.P., Meadows, L.A. Fisher, B., Matilla, S.S., and Russell, S. (2005) Robotic spotting of cDNA and oligonucleotide microarrays. Trends in Biotechnology, 23, 373 379. An overview of spotting techniques in creation of microarrays. Brown, P.O. and Botstein, D. (1999) Exploring the new world of the genome with DNA microarrays. Nature Genetics, 21, 33 37. An overview of gene microarrays. Curtis, R.K., Ore i , M. and Puig, V. (2005) Pathways to the analysis sc of microarray data. Trends in Biotechnology, 23, 429 435. An excellent review of data analysis aspects of microarrays. Ahn, N.G., and Resing, K.A. (2001) Towards the phosphoproteome. Nature Biotechnology 19, 317 318. An assessment of methods for proteome analysis. Conrads, T.P., Issaq, H.J. and Veenstra, T.D. (2002) New tools for quantitative phosphoproteome analysis. Biochemical and Biophysical Research Communication 25, 885 890. Dalle-Donne, I., Scaloni, A. and Butter eld, D.A. (Eds.) (2006) Redox Proteomics: From Protein Modi cations to Cellular Dysfunction and Diseases. John Wileyand Sons, Hoboken, NJ, USA. A comprehensive volume on proteomics approaches to redox modi cations. Guan, J.-Q. and Chance, M.R. (2005) Structural proteomics of macromolecular assemblies using oxidative footprinting and mass spectrometry. Trends in Biochemical Sciences 30, 583 592. Review of MS for detection of protein lesions arising from oxidation. Sheehan, D. (2006) Detection of redox-based modi cation in two dimensional electrophoresis proteomic separations. Biochemical and Biophysical Research Communications 349, 455 462. A review of methods for nding oxidatively modi ed proteins in two dimensional SDS PAGE separations. Wuhrer, M., Deelder, A.M. and Hokke, C.H. (2005) Protein glycosylation analysis by liquid chromatography-mass spectrometry. Journal of Chromatography B. 825, 124 133. Application of LC-MS to analysis of glycosylation of proteins.

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[40, 41] They are small physical devices that contain a tiny droplet of free electrons [186, 187, 188, 189, 190]: small metal or semiconductor boxes that hold a speci ed number of electrons (the number can be adjusted from zero the several hundred by changing the dot s electrostatic status) See Figure 411 [191, 192] (QDs generally look more like pyramids than actual dots) QDs are a grouping of atoms so small that the addition or removal of an electron will change its properties in a signi cant way [36] QDs are a semiconductor structures where the electron wave function is con ned in all three dimensions by the potential energy barriers that form the QD s boundaries [52] Speci cally, QDs are semiconductor structures that con ne the electrons and holes to a volume of the order of 20 nm3 (or slightly larger in some cases).

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