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It may be that SHMO expectations are in error here and that the greater basicity of the carbonyl oxygen is simply a re ection of the greater stability of the protonated carbonyl intermediate as compared to the protonated alkene, as discussed in 7 186 Besseau, F; Lucon, M; Laurence, C; Berthelot, M, J Chem Soc Perkin, 1998, 2, 101 108 187 Saied, O; Bachand, B; Wuest, J D, Can J Chem, 1998, 76, 490 497 188 Rauk, A; Hunt, I R; Keay, B A, J Org Chem, 1994, 59, 6808 6816 189 For a study of hydride reductions, see Wu, Y-D; Tucker, J A; Houk, K N, J Am Chem Soc, 1991, 113, 5018, and references therein 190 Liebman, J F; Pollack, R M, J Org Chem, 1973, 38, 3444.



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and therefore zo is substituted by z' throughout. Expanding equation (2.43) for even elements gives

191 Hoz, S, J Org Chem, 1982, 47, 3545 192 Shustov, G V, Acad Sci U S S R Proc Chem, 1985, 280, 80..

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t is often said that the central processing unit or CPU is the brain of a computer It is a programmable device that carries out the instruction, logic, and mathematical calculations in a computer Great investments in time, effort, and money are made by some of the world s powerful corporations on the development of ever more capable CPUs Mid-2005 (the time during which this book is being written) is an exciting time in the world of X86 central processing units The industry is in transition between single-core and multi-core processors, and 64-bit computing is beginning to arrive at the consumer desktop As a result, there are more CPU choices for PCs than ever before, with multiple processor types from Intel, AMD, and VIA For an end user assembling his or her own system, the choices are somewhat more limited.

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An open-ended discussion of all the various CPU flavors available today will take far more time and space than we have here; however, the practical aspects of processors upon which to base your purchase choice for your HTPC is more pertinent to this book s discussion anyway This chapter quickly reviews what the CPU does and what specifications such as clock and bus speed and cache mean It examines the main processor options from AMD and Intel, along with a comparison of their features, their strengths, and their weaknesses You also learn about what it takes to keep the various processors cool, about heat sinks, fans, and airflow, and how cooling ties in with aspects of case design and even the power supply Overclocking and undervolting are also examined During these discussions, you learn if there are any traits of processors that are of particular importance for an HTPC.

for t R+ with equality iff A is normal. (Any A Cn n is normal iff AH A = AAH .) Thus, it appears that normal matrices are generally the least troublesome with respect to computing eAt . From the de nition of a normal matrix we see that real-valued, symmetric matrices are an important special case. Of the less dubious means to compute eAt , Golub and Van Loan s algorithm 11.3.1 [4] is suggested. It is based on Pad approximation, which is the use of e rational functions to approximate other functions. However, we will only refer the reader to Ref. 4 (or Ref. 7) for the relevant details. A version of Algorithm 11.3.1 [4] is implemented in the MATLAB expm function, and MATLAB provides other algorithm implementations for computing eAt . 11.4 THE POWER METHODS In this section we consider a simple approach to determine the eigenvalues and eigenvectors of A Rn n . The approach is iterative. The main result is as follows. Theorem 11.11: Let A Rn n be such that (a) A has n linearly independent eigenvectors x (k) , corresponding to the eigenpairs {( k , x (k) )|k Zn }. (b) The eigenvalues satisfy n 1 R with | n 1 | > | n 2 | | n 3 | | 1 | | 0 | ( n 1 is the dominant eigenvalue). If y0 Rn is a starting vector such that

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