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The rate-determining step, ``M,'' may be a single metal such as Na or Li or a complex such as AlH3 (as in LiAlH4 ). Using a two-orbital interaction diagram (assume M Li), show which orbitals are involved in the above step. Predict the most favorable geometry for the approach of the reagents. (For an interesting variation of this reaction using a chiral aluminum hydride to e ect enantioselective reduction, see Noyori, R.; Tomino, I.; Yamada, M.; Nishizawa, M., J. Am. Chem. Soc., 1984, 106, 6717 6725.) 5. Explain the higher reactivity of acetone (propanone) compared to methyl acetate (CH3 CO2 CH3 ) toward reduction by sodium borohydride.



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If you start an editing command before selecting an object, the command responds with the Select objects: prompt. When you pick an object to select it, AutoCAD or AutoCAD LT highlights it, usually by making the object dashed, as shown in Figure 9-1.

Average energy (MeV) 0.024 0.16 0.22 0.31 0.83 2 3.27 5 4.5 2.3 14.1

Photoshop novices often misunderstand the rectangular and elliptical marquee tools and expect them to create filled and stroked shapes. In the past, the program offered no tools for creating such shapes you had to draw a geometric marquee and then fill or stroke the selection. Now Photoshop provides the shape tools, which can create filled vector and raster shapes. You can apply strokes and other effects to these shapes if you like. 14 takes you on a guided tour of the shape tools.





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You can also click each field and enter the tab order number for each one in the tab field in the Inspector. This method has more steps, so you probably won t choose it initially. However, it may come in handy for editing the tab order.

Dandliker R, E Zimmermann, and G Frosio, Electronically Scanned White-Light Interferometry: A Novel Noise-Resistant Signal Processing, Opt Lett, 17, 679 681 (1992) Danielson B L and CY Boisrobert, Absolute Optical Ranging Using Low Coherence Interferometry, Appl Opt, 30, 2975 2979 (1991) Davidson M, K Kaufmn, I Mazor, and F Cohen, An Application of Interference Microscopy to Integrated Circuit Inspection and Metrology, Proc SPIE, 775, 233 247 (1987) Debnath S K and M P Kothiyal, Optical Pro ler Based on Spectrally Resolved White Light Interferometry, Opt Eng, 44, 013606 (2005) Debnath S K, M P Kothiyal, J Schmit, and P Hariharan, Spectrally Resolved White-Light Phase-Shifting Interference Microscopy for Thickness Pro le Measurement of Transparent Thin-Film Layers on Patterned Substrates, Opt Express, 14, 4662 4667 (2006) Deck L L, Fourier-Transform Phase-Shifting Interferometry, Appl Opt, 42, 2354 2365 (2003) Deck L and P.

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Preventive measures This activity can be as simple as performing household-type activities such as making sure that ventilation vents on equipment are free and clear If there are lters involved, they should be changed at the manufacturer s recommended interval An occasional survey of all equipment within the network should be taken to ensure that no obstructions block vents or fan intakes General housekeeping should be performed to eliminate any clutter that may have gathered around equipment The serviceability of electronic equipment is directly proportional to how well it is kept to its normal operational range If devices become stressed due to excessive heat, they will eventually fail Good housekeeping practices can boost the reliability of the network while eliminating unnecessary costs A major preventive measure that often is forgotten is the saving of con guration les related to a piece of equipment.

de Groot, High-Speed Noncontact Pro ler Based on Scanning White-Light Interferometry, Appl Opt, 33, 7334 8 (1994) Decker J E, J R Miles, A A Madej R Siemsen, K J Siemsen, S de Bonth, K Bustraan, S Temple, and J R Pekelski, Increasing the Range of Unambiguity in Step-Height Measurement with Multiple-Wavelength Interferometry-Application to Absolute Long Gauge Block Measurement, Appl Opt, 42, 5670 5678 (2003) de Groot P J, Three-Color Laser-Diode Interferometer, Appl Opt, 30, 3612 3616 (1991) de Groot P J, Chromatic Dispersion Effects in Coherent Absolute Ranging, Opp Lett, 17, 898 900 (1992) de Groot P J, Extending the Unambigous Range of Two-Color Interferometers, Appl Opt, 33, 5948 5953 (1994) de Groot P J, Measurement of Transparent Plates with Wavelength-Tuned PhaseShifting Interferometry, Appl Opt, 39, 2658 2663 (2000) de Groot P J.

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