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Every SDP is identified by a numeric label. It s a best practice to design or pick a convention for the numbering scheme, and stick to it! we ll use the convention of two digits: the first digit for the near end router and the second digit for the far end router. As an example, an SDP from PE1 to PE2 will be labeled 12. 3. On PE1, configure an SDP to PE2; on PE2, configure an SDP to PE1. For the first attempt, do not use the parameter create when defining the SDP. For the second attempt, don t forget to use the attribute mpls! Like LDP, the default state for an SDP is disabled. Don t forget the no shutdown command.



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14) can be used to calculate the dependence of $2(o) and 02(w) on A ^ The electrical double layer has, of course, a similar structure when a single electrolyte is present in the distribution equilibrium in the system It is interesting that the experimentally measured zero-charge potential is practically identical with the value of A 0 = 0, calculated using the TATB assumption (3264) This fact helps to justify the use of this assumption The electrical double layer at the solid electrolyte-electrolyte solution interface has been studied primarily in colloid suspensions, especially for silver halides The potential difference between the solid and liquid phases can be changed by changing the concentration of the 'potential-determining ions', ie either the silver or halide ions In solid oxide suspensions, hydrogen ions act as potential-determining ions.





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*B:PE1# configure service *B:PE1>config>service# sdp 12 mpls MINOR: CLI create is mandatory while creating SDP. *B:PE1>config>service# sdp 12 mpls create *B:PE1>config>service>sdp$ far-end 150.10.0.1 *B:PE1>config>service>sdp$ ldp *B:PE1>config>service>sdp$ no shutdown *B:PE1>config>service>sdp$

The zero-charge potential of this system can be found from the dependence of the electrophoretic mobility (see Section 454) on the concentration of potential-determining ions, ie it corresponds to zero electrophoretic mobility With this type of interface the structure of the electrical double layer depends to a marked degree on the preparation and thus also on the final structure of the solid phase Two cases are most often observed: (a) Ions are adsorbed from solution on the surface of the solid phase and counter ions form a diffuse layer..

4. After both SDPs have been configured, verify that they are both admin and operationally Up. (In some circumstances, you may need to wait a few moments before the SDPs will be Up.) If not, confirm that you have entered all the parameters correctly.

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(b) The electrical double layer has a structure similar to ITIES, but the diffuse layer in the solid becomes a simple Helmholtz layer because of the high concentration of ions. It should, however, be noted that the electrical double layer at the metal-fused electrolyte interface does not have this character, in spite of the ion concentration being high. In this system, the space charge includes several ion layers at the interface. 4.5.3 Electrokinetic phenomena The adsorption of ions at insulator surfaces or ionization of surface groups can lead to the formation of an electrical double layer with the diffuse layer present in solution. The ions contained in the diffuse layer are mobile while the layer of adsorbed ions is immobile. The presence of this mobile space charge is the source of the electrokinetic phenomena.^ Electrokinetic phenomena are typical for insulator systems or for a poorly conductive electrolyte containing a suspension or an emulsion, but they can also occur at metal-electrolyte solution interfaces. Consider a solid surface in contact with a dilute electrolyte solution. The plane where motion of the liquid can commence is parallel to the outer Helmholtz plane but shifted in the direction into the bulk of the solution. The electric potential in this plane with respect to the solution is termed the

*B:PE1>config>service# show service sdp ============================================================= Services: Service Destination Points ============================================================= SdpId Adm MTU Opr MTU IP address Adm Opr Deliver Signal ------------------------------------------------------------12 0 9190 150.10.0.1 Up Up LDP TLDP ------------------------------------------------------------Number of SDPs : 1 ------------------------------------------------------------============================================================= *B:PE1>config>service#

electrokinetic potential (| | ^ |$2|)

5. Removing an SDP is the familiar two-step process: Shut down the SDP and delete it with no sdp. Remove one of the SDPs for practice.

Of the four electrokinetic phenomena, two (electroosmotic flow and the streaming potential) fall into the region of membrane phenomena and will thus be considered in 6. This section will deal with the electrophoresis and sedimentation potentials. If the electric field E is applied to a system of colloidal particles in a closed cuvette where no streaming of the liquid can occur, the particles will move with velocity v. This phenomenon is termed electrophoresis. The force acting on a spherical colloidal particle with radius r in the electric field E is 4^rerE02 (for simplicity, the potential in the diffuse electric layer is identified with the electrokinetic potential). The resistance of the medium is given by the Stokes equation (2.6.2) and equals 6jrr/rv. At a steady state of motion these two forces are equal and, to a first approximation, the electrophoretic mobility v/E is

*B:PE1>config>service# sdp 12 shutdown *B:PE1>config>service# no sdp 12 *B:PE1>config>service#

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