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priorities decrease in a counterclockwise manner when the face is viewed from the propagating center The re and si faces of a monomer such as propene are enantiotopic; that is, the products formed by additions of a propagating center to the two faces have opposite con gurations (The term prochiral has been used for a carbon atom such as the CHR carbon of a monomer molecule to indicate additions to the si and re face yield, respectively, one enantiomer or the other of a pair of enantiomers) The description in Fig 8-10 for isotactic polymerization could also have been shown with the R and H groups of the last monomer unit in the polymer chain reversed (R in back and H in front), in which case isotactic propagation consists of monomer always approaching the propagating center with its si face.



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The property of the initiator fragment that forces successive placements of monomer to occur with the same face is chirality There is a stereochemical t between initiator and monomer, which overrides the usual tendency toward moderate syndiotacticity The initiator in isotactic polymerization is usually a racemic mixture of two enantiomers One of the enantiomers yields isotactic polymer by forcing all propagations via the re face of monomer; the other enantiomer, via the si face The isotactic polymer structures formed from the enantiomeric initiators are the same polymer; that is, they are superposable (ignoring the effects of end groups) for most monomers (Exceptions are some ring-opening polymerizations, eg, propylene oxide, and 1,4-polymerizations of some substituted 1,3-dienes, eg, 1,3-pentadiene, where the two isotactic polymers are enantiomeric.

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) Isoselective initiators of the traditional Ziegler Natta type are heterogeneous, with chirality attributable to the chiral crystal lattice in the vicinity of the initiator active center The chirality of the homogeneous metallocene initiators resides in their molecular structures; thus, the initiator molecule is chiral Some chiral initiators have structures such that alternate monomer placements occur with opposite faces of the monomer to yield the syndiotactic polymer This is syndioselective polymerization proceeding with catalyst site control and is usually observed only with some homogeneous initiators, both traditional Ziegler Natta and metallocene When the initiator is achiral, the active sites can coordinate equally well (more or less) with either face of the incoming monomer This generally results in either atactic or syndiotactic polymers depending on the speci c interaction of the initiator fragment G, polymer chain end, and incoming monomer as well as the reaction temperature.

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Syndioselective polymerization occurs in systems where coordination accentuates the repulsive interactions between substituents on the polymer chain end and incoming monomer The driving force for syndiotactic placement is similar to that previously described for low-temperature polymerizations with free propagating centers, but the initiator exaggerates the situation Instead of obtaining a polymer with moderate syndiotacticity, say, 60% syndiotactic polymer, one may obtain 80% or 90% or higher syndiotacticity The syndiotacticity increases with decreasing polymerization temperature The exact nature of the initiator needed for isoselective polymerization differs depending on the monomer The ease of imposing catalyst site control on the entry of a monomer unit into the polymer chain increases with the ability of the monomer to coordinate with initiator and this depends on monomer polarity Monomers, such as (meth)acrylates and vinyl ethers, with polar functional groups take a strong role in the coordination process.

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Ethylene, a-ole ns, and other alkenes without polar functional groups have poorer coordinating power The result is that nonpolar monomers require the use of initiators with very strong coordinating power for isoselective polymerization For the traditional Ziegler Natta initiators, this requires heterogeneous initiators to impose the most severe restriction on entry of a monomer into the propagating chain Soluble traditional Ziegler Natta initiators can yield only atactic and syndiotactic polymers Heterogeneity is not required for isoselective polymerization with the metallocene initiators The required level of coordination can be achieved through the appropriate structure of the metallocene..

Now, neglecting spontaneous emission is only a reasonable approximation to a real laser in the steady state, and even then only if this steady state is far above threshold. Taking the limit t ~ 00 of (8.103) and (8.104) to obtain the steady state, we find thatl8 (Problem 8.7) lim Ca(t) = and lim Cb(7], t)

For polar monomers, heterogeneity is seldom a requirement for isoselective polymerization with traditional Ziegler Natta initiators; syndiotactic polymers are obtained only with the soluble initiators. Styrene and 1,3-dienes are intermediate in behavior between the polar and nonpolar monomer. These monomers undergo isoselective polymerization with both homogeneous and heterogeneous traditional Ziegler Natta initiators.

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