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Brougharn Bridge" is properly referred to as Broome Bridge. narned after a local family (see Graves's biography of Hamilton [267]).

Aldehydes and ketones are polymerized by both anionic and cationic initiators (Chap. 5). 3-1b-2 Effects of Substituents



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Figure C.3 The complex plane is generalized to three dimensions by introducing a second imaginary axis j. Just as multiplication by i rotates a vector along the real line out of its one-dimensional world into the second dimension, multiplication by j rotates such a vector out of the real line into the third dimension. Just as multiplication by i twice means rotating 180 degrees (Le., inverting the direction of the vector), multiplication by j twice must also mean rotating 180 degrees. So just as i 2 = -1, j2 must also be -1. But by which number can we mUltiply a vector on the ordinary imaginary line to rotate it out of this Jine into the new imaginary line





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Unlike the carbonyl linkage, the carbon carbon double bond undergoes polymerization by both radical and ionic initiators. The difference arises because the p-bond of a vinyl monomer can respond appropriately to the initiator species by either homolytic or heterolytic bond breakage:

3-4

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public DataSet GetExcel(string fileName) { Application oXL; Workbook oWB; Worksheet ... Value); // get WorkSheet object oSheet = (Microsoft.Office.Interop.

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lines rather than just one. Now we can go not only from the real line to anyone of the other two imaginary lines, but we can also go from one of the imaginary lines to the other imaginary line. The former is solved by our straightforward extension of the old idea of mUltiplying by i: To get from the real line to the new imaginary line, we just multiply by the new imaginary number j. The latter, however, is still unresolved. There are two key questions that we must answer in order to complete our three-dimensional generalization of the connection in two dimensions between multiplication of complex numbers and rotation: 1. By what number can we multiply a vector that lies on the i-imaginary line to rotate it to the j-imaginary line 2. Analogously, by what number can we multiply a vector that lies on the jimaginary line to rotate it to the i-imaginary line Let us concentrate on question 1 first. Clearly, this number cannot be real, for it would only change the length or invert the direction of the vector without making it leave the i-imaginary line. Neither can it be i nor j. It cannot be i, because ii = -1, which takes the vector to the real axis. It cannot be j because ji = j would imply that i = 1. So we are forced to assume the existence of a/ourth axis with a new unit number k, whose multiplication takes a vector on the i-imaginary line onto the j-imaginary line; that is, (C.7) ki = j. Being a fourth dimension, this new axis is at 90 degrees to the other axes. Then multiplication by k twice must mean a rotation of 180 degrees, which implies that

A wide range of carbon carbon double bonds undergo chain polymerization. Table 3-1 shows monomers with alkyl, alkenyl, aryl, halogen, alkoxy, ester, amide, nitrile, and heterocyclic substituents on the alkene double bond. Whether a vinyl monomer polymerizes by radical, anionic, or cationic initiators depends on the inductive and resonance characteristics of the substituent(s) present. The effect of the

To add a column break, click where you want the break to occur and then press + + .To remove a break, select .To return to a it and press one-column format, click the Columns button on the Page Layout tab and then select the single-column format.

this forth axis is also an imaginary axis; that is,

substituent manifests itself by its alteration of the electron-cloud density on the double bond and its ability to stabilize the possible radical, anion, or cation formed. Electrondonating substituents such as alkoxy, alkyl, alkenyl, and phenyl increase the electron density on the carbon carbon double bond and facilitate its bonding to a cationic species. Further,

(C.8)

+

Notice that in order for this scheme to make any sense, multiplication must be noncommutative8 ; otherwise, squaring (e.7), we would find k 2 = 1 instead of (C.8). At this point, the reader might be wondering whether we will find out next that in order to have a consistent scheme, we require yet another fifth, sixth, seventh dimension, and so on, never stopping. Well, part of the beauty of this is that four dimensions is just enough to make the entire scheme self-consistent, as we will show now. Multiplying (e.7) by k from the left and using (e.8), we find that kj = -i. (C.9)

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