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Jul 13, 2015 · Convert PDF to Word Using C# PdfBox: This third-party Nuget package will be used to read a PDF file. DocX: This package will be used to write a Word document.

TABLE 6-3 Relative Reactivities 1=r of Monomers with Various Polymer Radicalsa Polymer Radical Vinyl Vinyl Methyl Methyl Butadiene Styrene Acetate Chloride Methacrylate Acrylate Acrylonitrile 0.7 1.3 3.3 1.3 0.11 1.7 1.9 3.4 2.5 1.3 0.54 0.059 0.019 100 67 20 20 10 10 4.4 29 50 10 10 25 17 0.59 4 2.2 0.82 0.52 0.39 0.10 0.050 20 5.0 2 1.2 0.25 0.11 50 25 6.7 1.7 0.67 1.1 0.37 0.24



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As a result, we will take energy from the swing, damping its movement instead of giving energy to it to increase its movement But if we push it in its own rhythm, the swing can reach considerable heights very fast if we are not careful Anyone who has ever tried to push a child on a swing knows that This is the phenomenon of resonance Now that we have seen it in words, let us have a look at the mathematics of resonance The magnitude of the net force is mg sin 4>, where g is the local acceleration constant due to gravity and 4> is the angle the rope forms with the vertical (see Figure 25) If the amplitude of the swings is kept small so that 4> is small, we can approximate.





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Monomer 1,3-Butadiene Styrene Methyl methacrylate Methyl vinyl ketone Acrylonitrile Methyl acrylate Vinylidene chloride Vinyl chloride Vinyl acetate

"' ~~'.--.'.'Y~.,;~;., ~~ ( .

1=r values calculated from data of Table 6-2.

""_'\ -. .

Monomer (M2) 2,060 1,130 515 422 268 52 26 41,800 10,045 4,180 2,510 2,090 520 230 98,000 49,000 13,100 1,960 1,310 720 230 230,000 154,000 46,000 23,000 10,100 2,300

Polymer Radical Methyl Methyl Vinyl 1,3-Butadiene Acrylonitrile Q e Styrene Acrylate Methyacrylate Vinyl Acetate Chloride 319,000 550,000 110,000 225,000 187,000 11,000 6,490 1.70 0.50 1.00 0.80 0.78 0.40 0.48 1.23 0.45 0.64 0.16 0.056 0.026 0.88

,. 1..:..

1 2 3 4

1,3-Butadiene Styrene Methyl methacrylate Acrylonitrile Methyl acrylate Vinyl chloride Vinyl acetate

--:- ... - '

100 70 130 330 130 11

Any field density matrix p(t) can be written as a linear combination of diagonal coherent-state density matrices 11 [236,583]

280 165 314 413 215 9.7 3.4

P(a)

k12 values calculated from data in Tables 3-11 and 6-3.

(6.62)

of certain comonomer pairs. Table 6-3 and other similar data show that substituents increase the reactivity of a monomer toward radical attack in the general order

(6.63)

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The order of monomer reactivities corresponds to the order of increased resonance stabilization by the particular substituent of the radical formed from the monomer Substituents composed of unsaturated linkages are most effective in stabilizing the radicals because of the loosely held p-electrons, which are available for resonance stabilization Substituents such as halogen, acetoxy, and ether are increasingly ineffective in stabilizing the radicals since only the nonbonding electrons on halogen or oxygen are available for interaction with a radical The spread in the effectiveness of the various substituents in enhancing monomer reactivity is about 50 200-fold depending on the reactivity of the radical The less reactive the attacking radical, the greater is the spread in reactivities of the different monomers The effect of a second substituent in the 1-position as in vinylidene chloride is approximately additive.

So for an infinitesimal time interval c5t,

The order of radical reactivities can be obtained by multiplying the 1=r values by the appropriate propagation rate constants for homopolymerization (k11 ) This yields the values of k12 for the reactions of various radical monomer combinations (Table 6-4) The k12 values in any vertical column in Table 6-4 give the order or monomer reactivities as was the case for the data in Table 6-3 The data in any horizontal row give the order of radical reactivities toward a reference monomer (The Q1 and e1 values in the last two vertical columns should be ignored at this point; they will be considered in Sec 6-3b-4) As with monomer reactivities it is seen that the order of radical reactivities is essentially the same irrespective of the monomer used as reference The order of substituents in enhancing radical reactivity is the opposite of their order in enhancing monomer reactivity.

Click the File tab. Click New. Click Blank presentation. Click Create. PowerPoint creates a new presentation with one blank slide.

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