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We take the amplitude of the incident positive-frequency plane-wave component to be [169] (2.176) where aa(k) is the annihilation operator of the mode with wave vector k and polarization a, and (2.177) is the modified vacuum field strength. 41 We obtain the positive-frequency part of the electric field, summing up all the modified plane waves, by varying the direction and polarization of the incident plane wave,



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Thermoplastic polyurethanes are used in applications such as wire insulation, automobile fascia, footwear (lifts, ski boots, football cleats), wheels (industrial, skateboard), and adhesives, where such properties are not important Two types of macrodiols are used in the synthesis of TPU polyesters, as described in Eqs 2-197 and 2-198, and a,o-dihydroxypolyethers obtained by ring-opening polymerizations (Chap 7) of ethylene and propylene oxides and tetrahydrofuran (THF) The polyester-based TPU is tougher and has better oil resistance while the polyether-based TPU shows better low temperature exibility and better hydrolytic stability Spandex (trade name: Lycra) bers are.

time maintains the radical concentration at approximately a constant value and is equivalent to polymerization under constant illumination at an intensity 1= 1 r times that actually used [Flory, 1953; Walling, 1957]. The ratio of the average polymerization rate Rp 1 at very short cycle time to the steady-state rate is given by





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where the integration is restricted to half space (I.e., positive k z ), because of the perfect plate at z = 0, and the annihilation and creation operators obey the usual continuum commutation relations (2.179)

Rp 1 1 Rp s 1 r 1=2 3-159

41There is an extra factor 2 in comparison to the free-space case because of the perfect plate at z eliminates half the space [35,169,448,495\.

Thus, the average polymerization rate increases by a factor of 1 r 1=2 as the cycle (pulse) frequency increases from a low value to a very high value compared with 1=ts . The mathematical treatment of pulsing illumination has been described [Briers et al., 1926]. After a number of cycles, the radical concentration oscillates uniformly with a constant radical concentration M 1 at the end of each light period of duration t and a constant radical concentration M 2 at the end of each dark period of duration t0 rt. The two radical concentrations are related by

The label f3 stands either for cav, the field between the plates, or for out, the field outside. The mode functions obtained by our scattering method, also known as the modes of the universe, are

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tanh 1 M 1 M 2 t tanh 1 ts M s M s 3-160

(2.180)

M s M s rt M 2 M 1 ts 3-161

Note: As you drag over each effect in the menu, the picture displays what the effect looks like when you apply it.

e~~~(r,k) = ik vaceiK..r.e1l cosBsinkzz,

The maximum and minimum values of the ratios M 1 = M s and M 2 = M s can be calculated from Eqs. 3-160 and 3-161 for given values of r and t=ts . The average radical concentration M over a cycle or several cycles is given by

(2.181) (2 . 182)

t0

,"caY r, , <:' . "11,2 (k) = -Zvvac eiK..r.e II sin BCOS k zZ,

3-162

where the rst integral (for the light period) is given by Eq. 3-160 and the second integral (for the dark period) is given by Eq. 3-161. Evaluation of the integrals in Eq. 3-162 yields

,"out (k) =tZ 1\ K.vvace iK..r.e .L [. k zz+t'2 r .d B) sinusin (k zZ-U , .. ' <:' ~)] r, sin t.L(B) . ~ .

! M ts M 1 = M 2 M 1 = M s r 1 1 1 ln M s t 1 M 1 = M s 3-163

(2.183)

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