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It is dif cult to nd crosslinking systems that are ideal in that all functional groups are of equal reactivity and intramolecular cyclization is negligible The crosslinking of vinyl terminated poly(dimethylsiloxane) polymers with tri- and tetrafunctional silanes appears to be an exception Thus the calculated and experimental pc values were 0578 and 0583, respectively, for the tetrafunctional silane and 0708 and 0703, respectively, for the trifunctional silane (with r 0:999) [Valles and Macosko, 1979] Although both the Carothers and statistical approaches are used for the practical predication of gel points, the statistical approach is the more frequently employed The statistical method is preferred, since it theoretically gives the gel point for the largest-sized molecules in a size distribution From the practical viewpoint the use of the Carothers approach alone can be disastrous, since the Carothers approach always predicts a higher pc than observed.



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The slides ofthis course are available on the conference Web site: http://leopardicmpsnsitlEricel 504 T C Ralph and C M Savage Squeezed light from conventionally pumped multilevellasers Optics Letters, 16(14):1113-1115, July 1991 505 T C Ralph and C M Savage Squeezed light from a coherently pumped fourlevel laser Physical Review A, 44(11):7809-7814, December 1, 1991..

Crosslinked polymer becomes intractable above pc ; the reaction must be stopped at an extent of reaction below pc before starting the technological step of fabricating the polymer into the shape of nal desired product (see Sec 2-12) Further, the statistical approach offers a greater possibility of adaption to various systems of reactants as well as the inclusion of corrections for the nonapplicability of the equal reactivity assumption and the occurrence of intramolecular reactions Equation 2-148 and its modi cations have been used extensively in the technology of crosslinked polymers..





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506 P Rastall Quaternions in relativity Reviews of Modem Physics, 36(3):820832, July 1964 The definition of Hermitian conjugate of a quaternion used in this paper differs from ours by a multiplicative factor of -l 507 J R Ray Dissipation and quantum theory Lettere al Nuovo Cimento, 25(2):4750, May 12, 1979 See also the erratum: J R Ray, Lettere al Nuovo Cimento, 26(2):64, September 8, 1979 508 J R Ray Lagrangians and systems they describe: How not to treat dissipation in quantum mechanics American Journal ofPhysics, 47(7):626-629, July 1979 509 J W S Rayleigh The Theory of Sound, volume 2 Dover, New York, 1945 510 Lord Rayleigh On maintained vibrations Philosophical Magazine, 15:229235, 1883 Reprinted in Scientific Papers by John William Strutt, Baron Rayleigh, DSc, FRS.

The statistical approach has been applied to systems containing reactants with functional groups of unequal reactivity [Case, 1957; Macosko and Miller, 1976; Miller and Macosko, 1978; Miller et al., 1979]. In this section we will consider some of the results for such systems. Figure 2-15 shows a plot of M w vs. extent of reaction for the various values of s at r 1 for the system

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, Honorary Fellow of Trinity College, Cambridge, Professor of Natural Philosophy in the Royal Institution, volume II, 1881-1887, Cambridge University Press, Cambridge, 1900, pp 188-193 Online at the internet archive (under Strott): http://wwwarchiveorg 511 S Raynaud, A Lambrecht, C Genet, and M-T Jaekel Quantum vacuum fluctuations Comptes Rendus de l'Academie des Sciences Serie IV Physique Astrophysique, 2(9): 1287-1298, November 2001 512 M Razavy On the quantization of dissipative systems Zeitschriftfiir Physik B, 26:201-206, 1977 513 M Razavy Hamilton's principal function for the Brownian motion of a particle and the SchrOdinger-Langevin equation~ Canadian Journal of Physics, 56(3):311-320, March 1978 514 E Recami Possible physical meaning of the photon wave-function, according to Ettore Majorana In Hadronic Mechanics and Non-potential Interactions, pp 231-238 Nova Science, New York, 1990 515 F Reif Fundamentals of Statistical and Thermal Physics McGraw-Hill Series in Fundamentals of Physics: An Undergraduate Textbook Program.

Fig. 2-15 M w versus extent of reaction for polymerization of A3 with B B0 for different s values. After Miller and Macosko [1978] (by permission of American Chemical Society, Washington, DC).

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