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DocX - John Atten had an excellent blog post and series on creating and manipulating Word Documents with C# using the open - source DocX ... unhindered monomers.) This order of reactivity concisely summarizes the data in Tables 6-3 and 6-4 as well as many homopolymerization data. It is clear that monomers without stabilizing substituents (e.g., vinyl chloride or vinyl acetate) will self-propagate faster than those with stabilizing substituents (e.g., styrene) (Reaction 6-51a versus 6-51c). Copolymerization, on the other hand, will occur primarily between two monomers with stabilizing substituents or between two monomers without stabilizing substituents. The combination of a monomer with a stabilizing substituent and one without (e.g., styrene vinyl acetate) yields a system in which a combination of Reactions 6-51b and 6-51d is required to have facile copolymerization. This does not occur, since Reaction 6-51d is very slow. Thus in the styrene vinyl acetate system copolymerization is not ef cient, since styrene radical is too unreactive to add to the unreactive vinyl acetate monomer. 6-3b-2 Steric Effects open pdf in word c#: C# .NET Word Document Processing API - Aspose aspose convert pdf to word c# I want to convert pdf to Word using C# | The ASP . NET Forums
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More from SautinSoft Team The rates of radical monomer reactions are also dependent on considerations of steric hindrance. This is easily observed by considering the reactivities of di, tri-, and tetrasubstituted ethylenes in copolymerization. Table 6-5 shows the k12 values for the reactions of various chloroethylenes with vinyl acetate, styrene, and acrylonitrile radicals. The effect of a second substituent on monomer reactivity is approximately additive when both substituents are in the 1- or a-position. However, a second substituent when in the 2- or b-position of the monomer results in a decrease in reactivity due to steric hindrance between it and the radical to which it is adding. Thus 2 10-fold increases and 2 20-fold decreases in the reactivities of vinylidene chloride and 1,2-dichloroethylene, respectively, are observed compared to vinyl chloride. Although the reactivity of 1,2-disubstituted ethylenes in copolymerization is low, it is still much greater than their reactivity in homopolymerization. It was observed in Sec. 3-9b-3 that the steric hinderance between a b-substituent on the attacking radical and a substituent on the monomer is responsible for the inability of 1,2-disubstituted ethylenes to homopolymerize. The reactivity of 1,2-disubstituted ethylenes toward copolymerization is due to the lack of b-substituents on the attacking radicals (e.g., the styrene, acrylonitrile, and vinyl acetate radicals). A comparison of the cis- and trans-1,2-dichloroethylenes shows the trans isomer to be the more reactive by a factor of 6 [Dawson et al., 1969]. This is a general phenomenon observed in comparing the reactivities of cis- and trans-1,2-disubstituted ethylenes. The cis isomer, which is usually also the less stable isomer, is the less reactive one toward reaction with a radical. The difference in reactivity has been attributed to the inability of the cis isomer to pdf to word c# C# PDF to Word SDK: How to convert, change PDF document to ...
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How to convert DOC into other formats using C# · http://dotnetf1.blogspot.com/2008/07/convert-word-doc-into-pdf-using-c-code.html. PowerPoint displays the current slide in the presentation. To view a particular slide, you can click the slide in the Slides tab. To close the tabs pane entirely and free up on-screen workspace, you can click the . The corresponding components of the density matrix obey the following differential equations derived from (6.69): TABLE 6-5 Rate Constants k12 for Radical Monomer Reactionsa Polymer Radical Vinyl Acetate Styrene Acrylonitrile 10,000 23,000 365 2,320 3,480 338 9.7 89 0.79 4.5 10.3 0.83 725 2,150 29 4.2 = ig (P12 - P2t) , Monomer Vinyl chloride Vinylidene chloride cis-1,2-Dichloroethylene trans-1,2-Dichloroethylene Trichloroethylene Tetrachloroethylene (6.73) (6.74) k12 values calculated from data in Tables 3-11 and 6-2 and Eastman and Smith [1976]. achieve a completely coplanar conformation in the transition state a requirement for resonance stabilization of the newly formed radical by the substituent. The data on the reactivities of trichloroethylene and tetrachloroethylene further illustrate the competitive effects of substitutions on the 1- and 2-positions of ethylene. Trichloroethylene is more reactive than either of the 1,2-dichloroethylenes but less reactive than vinylidene chloride. Tetrachloroethylene is less reactive than trichloroethylene analogous to the difference in reactivities between vinyl chloride and 1,2-dichloroethylene. The case of poly uoroethylenes is an exception to the generally observed large decrease in reactivity with polysubstitution. Tetra uoroethylene and chlorotri uoroethylene show enhanced reactivity due apparently to the small size of the uorine atoms. 6-3b-3 Alternation; Polar Effects and Complex Participation P22) , convert pdf to word c# code ASP.NET - Convert PDF to TXT or HTML in C# with iTextSharp
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