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since v1 log rS1 and v2 log rS2 . The values of v and u for a monomer are obtained from monomer reactivity ratios for copolymerization of that monomer with a series of reference monomers. A plot of the data according to Eq. 6-60a as [log r12 log r1S ] versus p1 yields a straight line whose slope is u2 and intercept on the y-axis is v2 . Table 6-8 shows values of the various parameters needed to calculate monomer reactivity ratios from Eqs. 6-60 and 6-62 [Jenkins and Jenkins, 1999]. The monomers in Table 6-8 are lined up in order of their u values. The Patterns of Reactivity scheme, like the Q e scheme, is an empirical scheme. Monomer reactivity ratios calculated by the patterns of reactivity scheme are generally closer to experimental values than those calculated by the Q e scheme, which supports the rationale of assigning different polarity values to a monomer and the radical derived from the monomer.



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RECOMMENDED READING For a discussion of atomic stability where coupling with the radiation field is neglected and only the Coulomb potential is considered, see [175, 177, 409. 575]. There are several approximations and assumptions in the Weisskopf-Wigner approach. For a detailed study of these and alternative improvements on the original Weisskopf- Wigner theory. see [7, 144, 360, 555]. For a discussion of renormalization in the context of atomic physics, I refer the reader to Weisskopf [630], Welton [632], Dalibard et al. [131], and Haroche [274]. For a thorough discussion of the two-level atom approximation, see Allen and Eberly [13].

TABLE 6-8 Patterns of Reactivity Parameters for Monomersa Monomer Ethyl vinyl ether Styrene a-Methylstyrene 1,3 Butadiene Isoprene Vinyl acetate Vinyl chloride 4-Vinylpyridine Methacrylic acid 2-Vinylpyridine Methyl methacrylate Vinylidene chloride Ethylene Acrylamide Methacrylonitrile Chloroprene Methyl acrylate Methyl vinyl ketone Diethyl maleate Acrylonitrile Diethyl fumarate Maleic anhydride





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Cavity Quantum Electrodynamics: The Strange Theory of Light in a Box Sergio M. Dutra Copyright 2005 John Wiley & Sons, Inc.

r1 S 0.05 1.00 0.60 1.20 1.84 0.02 0.055 0.69 0.524 1.26 0.46 0.108 0.05 0.70 0.33 6.91 0.18 0.32 0.04 0.04 0.06 0.011

... zu jener Zeit ... elektrische bezw. magnetische "Feldstiirken" und "Verschiebungen" wurden als gleich element are Grossen behandelt, der leere Raum als Spezialfall eines dielektrischen Korpers. Die Materie erschien als Thliger des Feldes, nicht der Raum .... Es war das grosse Verdienst von H. A. Lorentz, dass er hier in iiberzeugender Weise Wandel schur. 1m Prinzip gibt es nach ihm ein Feld nur im leeren Raume. Die atomistisch gedachte Materie ist einziger Sitz der elektrischen Ladungenj zwischen den materiellen Teilchen ist leerer Raum, der Sitz des elektromagnetischen Feldes ... Dielektrizitat, Leitungsfahigkeit, etc. sind ausschliesslich durch die Art der mechanischen Bindung der Teilchen bedingt, aus welchen die Korper bestehen. 1 -Albert Einstein [184]

r1 A 0.06 0.38 0.143 0.07 0.45 0.05 0.045 0.375 0.2 0.44 1.32 0.32 0.05 1.10 1.67 5.18 0.85 1.57 0.05 1.00 0.05 0.05

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There are two main versions of classical electrodynamics. The first was originally created by Maxwell and is now referred to as macroscopic electrodynamics. It involves four vectorial field quantities in a material medium: the electric field E, the magnetic field M, the electric displacement D, and the magnetic induction B. The

rA 1 0.69 0.04 0.047 0.036 0.03 4.78 3.29 0.10 0.04 0.10 0.138 0.64 7 0.90 0.43 0.05 1.42 0.61 16 1.00 9 6

4 3 4

1Translation: .. . at that time . . . electric or magnetic "field intensities" and "displacements" were treated as equally elementary variables, empty space as a special instance of a dielectric body. Matter appeared as the bearer of the field, not space . .. . It was the great merit of H. A. Lorentz that he brought about a change here in a convincing fashion. In principle a field exists, according to him, only in empty space. Matter-considered as atoms-is the only seat of electric charges; between the material particles there is empty space, the seat of the electromagnetic field .... Dielectricity, conductivity, etc. are determined exclusively by the type of mechanical tie connecting the particles, of which the bodies consist.

rS 1 100 1.00 1.1 0.64 0.458 48 18.7 0.52 0.24 0.53 0.5 1.79 14.9 1.20 0.38 0.038 0.75 0.29 7.03 0.38 0.33 0.36

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