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Nylon 6 is produced commercially, accounting for almost one-third of all polyamides (Sec. 2-8f). Nylons 11 and 12 are specialty polyamides, which nd use in applications requiring higher moisture resistance and hydrolytic stability. Lactams are named in several ways. They are named as alkanolactams by the IUPAC substitutive system, such as 3-propanolactam, 4-butanolactam, 5-pentanolactam, and 6-hexanolactam, respectively, for the 4-, 5-, 6-, and 7-membered rings, respectively. An alternate IUPAC method, the specialist heterocyclic nomenclature system, names these lactams as 2-azetidinone, 2-pyrrolidinone, 2-piperidinone, and hexahydro-2H-azepin-2-one, respectively. These lactams are also known by the trivial names b-propiolactam, a-pyrrolidone (g-butyrolactam), a-piperidone (d-valerolactam), and E-caprolactam, respectively.



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iDiTect Word to PDF Converter can be integrated in any .NET Winforms, WPF and ASP.NET web applications, to convert Word documents to PDF in a simple ...

You can use the Navigation pane, on the left, to open various database objects. You can collapse the pane to increase the on-screen workspace; simply click the Shutter Bar Open/Close button ( ). Click the button again to expand the pane.

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A variety of protonic and Lewis acids initiate the cationic polymerization of lactams [Bertalan et al., 1988a,b; Kubisa, 1996; Kubisa and Penczek, 1999; Puffr and Sebenda, 1986; Sebenda, 1988]. The reaction follows the mechanism of acid-catalyzed nucleophilic substitution reactions of amides. More speci cally, polymerization follows an activated monomer mechanism. Initiation occurs by nucleophilic attack of monomer on protonated (activated) monomer (XXIV) to form an ammonium salt (XXV) that subsequently undergoes proton exchange with monomer to yield XXVI and protonated monomer. The conversion of XXIV to XXV involves several steps attachment of nitrogen to C , proton transfer from





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(7.162) To obtain the electric field, we need to find the polarization and use it in (7.59). The polarization is given by (7.2) in terms of the operators iJ and iJt. So we have to find iJ in terms of C(w) and ct(w). Inverting (7.145) as in Problem 7.4, we find that

7-51

one N to the other N, ring opening of the HO-containing ring, and transfer from HO C to N with formation of XXV. Some literature references present variations of the preceding equation whereby protonation of lactam is shown as occurring at nitrogen. This does not correspond to the generally accepted mechanism for acid-catalyzed substitution reactions of amides, such as hydrolysis of acetamide. The available data on such reactions are consistent with protonation occurring almost exclusively at the carbonyl oxygen [Lowry and Richardson, 1987]. Propagation follows in a similar manner as a nucleophilic attack by the primary amine end group of a growing polymer chain (XXVII) on protonated monomer to yield XXVIII,

iJ(lI)

(n 1)

dw {f3Hw, II)C(w) - fh(w, lI)ct(w)}.

1-7

(7.163)

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How to convert PDF to Word in C# - YouTube
Nov 8, 2012 · PDF Focus.Net - How to convert PDF to Word using C#. SautinSoft.Duration: 4:17 Posted: Nov 8, 2012

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These polymers do not contain a functional group within the polymer chain but are classi ed as condensation polymers, since water is split out during the polymerization process. Another example is poly( p-xylene), which is produced by the oxidative coupling (dehydrogenation) of p-xylene:

Substituting this equation in (7.138), we obtain (7.164) Thus, after some algebra,

1-8

To open an existing database, click the File tab, click Recent and click the database in the Recent Databases list. If the database is not listed in the Recent Databases list, click the File tab, choose Open to launch an Open dialog box, locate and select the database file and click Open.

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In summary, a polymer is classi ed as a condensation polymer if its synthesis involves the elimination of small molecules, or it contains functional groups as part of the polymer chain, or its repeating unit lacks certain atoms that are present in the (hypothetical) monomer to which it can be degraded. If a polymer does not ful ll any of these requirements, it is classi ed as an addition polymer. 1-1b Polymerization Mechanism

(9.55)

In addition to the structural and compositional differences between polymers, Flory [1953] stressed the very signi cant difference in the mechanism by which polymer molecules are built up. Although Flory continued to use the terms condensation and addition in his discussions of polymerization mechanism, the more recent terminology classi es polymerizations into step and chain polymerizations. Chain and step polymerizations differ in several features, but the most important difference is in the identities of the species that can react with each other. Another difference is the manner in which polymer molecular size depends on the extent of conversion. Step polymerizations proceed by the stepwise reaction between the functional groups of reactants as in reactions such as those described by Eqs. 1-1 through 1-3 and Eqs. 1-6 through 1-8. The size of the polymer molecules increases at a relatively slow pace in such polymerizations. One proceeds from monomer to dimer, trimer, tetramer, pentamer, and so on

. (9.56)

Monomer Dimer + Dimer + Trimer + Trimer + + monomer monomer dimer monomer dimer dimer trimer tetramer tetramer pentamer hexamer

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PDF files is widely used for its convenience and safety on the Internet, meanwhile in daily work DOC files is more common in their degree of versatility and ...

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This document provides comprehensive Visual C# .NET samples for guiding developers to convert PDF to Word using Yiigo.Image for .NET.












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