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cross-talk between encoded pages Some azo chromophores exhibit biphotonic phenomena, which could be employed to enhance optical data storage 1264 Surface Mass Transport In 1995, a surprising and unprecedented optical effect was discovered in polymer thin lms containing the azo chromophore Disperse Red 1 (DR1) The Natansohn Rochon (Rochon et al, 1995) research team and the Tripathy Kumar collaboration (Kim et al, 1995) simultaneously and independently discovered a large-scale surface mass transport when the lms were irradiated with a light interference pattern In a typical experiment, two coherent laser beams, with a wavelength in the azo-absorption band, are intersected at the sample surface The sample usually consists of a thin spin-cast lm (10 1000 nm) of an amorphous azo polymer on a transparent substrate.



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String modifiedSentence; These above two lines declare objects of type String The object sentence is the string typed by the user and sent to the server The object modifiedSentence is the string obtained from the server and sent the user's standard output BufferedReader inFromUser = new BufferedReader(new InputStreamReader(Systemin)); The above line creates the stream object inFromUser of type BufferedReader The input stream is initialized with Systemin, which attaches the stream to the standard input The command allows the client to read text from its keyboard Socket clientSocket = new Socket("hostname", 6789); The above line creates the object clientSocket of type Socket It also initiates the TCP connection between client and server The variable "host name" must be replaced with the host name of the server (eg, "flingseasupennedu") Before the TCP connection is actually initiated, the client performs a DNS look up on the hostname to obtain the host's IP address The number 6789 is the port number You can use a different port number; but you must make sure that you use the same port number at the server side of the application As discussed earlier, the host's IP address along with the applications port number identifies the server process DataOutputStream outToServer = new DataOutputStream(clientSocketgetOutputStream()); BufferedReader inFromServer = new BufferedReader(new inputStreamReader(clientSocketgetInputStream()));





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The sinusoidal light interference pattern at the sample surface leads to a sinusoidal surface patterning, that is, a surface relief grating (SRG) These gratings were found to be extremely large, up to hundreds of nanometers, as con rmed by atomic force microscopy (AFM) The SRGs diffract very ef ciently, and in retrospect, it is clear that many reports of large diffraction ef ciency before 1995, attributed to birefringence, were in fact due to surface gratings The process occurs readily at room temperature (well below the Tg of the amorphous polymers used) with moderate irradiation (1 100 mW cm 2) over seconds to minutes The phenomenon is a reversible mass transport, not irreversible material ablation, since a at lm with the original thickness is recovered upon heating above Tg Critically, it requires the presence and isomerization of azobenzene chromophores Other absorbing but nonisomerizing chromophores do not produce SRGs.

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The above two lines create stream objects that are attached to the socket The outToServer stream provides the process output to the socket The inFromServer stream provides the process input from the socket (See diagram above) sentence = inFromUserreadLine(); The above line places a line typed by user into the string sentence The string sentence continues to gather characters until the user ends the line by typing a carriage return The line passes from standard input through the stream inFromUser into the string sentence outToServerwriteBytes(sentence + '\n'); The above line sends the string sentence augmented with a carriage return into the outToServer stream The augmented sentence flows through the client's socket and into the TCP pipe The client then waits to receive characters from the server modifiedSentence = inFromServerreadLine(); When characters arrive from the server, they flow through the stream inFromServer and get placed into the string modifiedSentence Characters continue to accumulate in modifiedSentence until the line ends with a carriage return character Systemoutprintln("FROM SERVER " + modifiedSentence);

file:///D|/Downloads/Livros/computa o/Computer%20Netw%20Approach%20Featuring%20the%20Internet/sockettcphtm (6 of 9)20/11/2004 15:51:59

Many other systems can exhibit optical surface patterning (Yamaki et al, 2000), but the amplitude of the modi cation is much smaller, does not involve mass transport, and usually requires additional processing steps The all-optical patterning unique to azobenzenes has been studied intensively since its discovery, yet there remains controversy regarding the mechanism The competing interpretations are evaluated in 4, where they are discussed at length Many reviews of the remarkable body of experimental results are available (Natansohn and Rochon, 2002; Delaire and Nakatani, 2000; Yager and Barrett, 2001; Viswanathan et al, 1999)..

System Design Review (SDR) System Requirements Review (SRR) Preliminary Design Review (PDR) Critical Design Review (CDR)

clientSocketclose(); This last line closes the socket and, hence, closes the TCP connection between the client and the server It causes TCP in the client to send a TCP message to TCP in the server (see Section 35)

This work is dedicated to Professors Almeria Natansohn and Sukant Tripathy, teachers and pioneers in the eld of azo polymers, who were unable to see the completion of this book.

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