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Apr 18, 2013 · Viewing PDF in Windows forms using C# How to open .Pdf file in C#.Net Win form Loading a ...Duration: 6:08 Posted: Apr 18, 2013

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where "I is the coefficient of friction and F is the random fluctuating force that the particle experiences due to the impact of the thermally agitated molecules of the liquid. Multiplying (8.22) by x and noticing that

Various endo-imino cyclic ethers (L) undergo cationic polymerization to yield poly(Nacylalkyleneimine)s (LI). The most widely studied monomers are the 2-substituted 2-oxazolines (m 2) (also referred to as 2-substituted-1,3-oxazolin-2-enes) [Culbertson, 2002;

2 2 2 d x 1d x (dx)2 dt2 = 2" dt 2 dt '

7-88

9 10

(8.23)



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Goethals, 1989a,b; Kobayashi and Saegusa, 1984, 1986; Kobayashi and Uyama, 2002; Kobayashi et al., 1990a,b; Kubisa, 1996; Tomalia and Killat, 1985]. Propagation proceeds via nucleophilic attack of monomer on the C bond of an oxazolinium ion: O

we obtain (8.24) Then Langevin takes the average of (8.24) over a large number of particles. He assumes that (xF) vanishes because the random force is uncorrelated to x and fluctuates equally between positive and negative values. He also notices that in thermal equilibrium,7 (8.25)

7-89

7This follows from the equipartition theorem (see. e.g. [515]).

LI can be hydrolyzed to the corresponding polyamine LII. This is the only route to linear polyethyleneimine (m 2) [Tanaka et al., 1983]. The polymerization of ethyleneimine yields a highly branched and cyclized product. exo-Imino cyclic compounds (LIII) such as iminocarbonates (Y O), 2-imino-1,3-oxzolidines (Y NR), and 2-iminotetrahydrofurans (Y CH2 ) have also been polymerized:





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where k is Boltzmann's constant and T is the absolute temperature. Thus, the average of (8.24) yields (8.26) dt mdt m Calling d(x 2 ) / dt X, we have a first-order nonhomogeneous ordinary differential equation for X. The general solution of this equation is an arbitrary linear combination of the particular solution with the solution of the associated homogeneous equation (the equation where the right-hand side of this equation is set to zero):

7-90

d( _ kT - x2) --+ C e -"ftlm dt 'Y '

An alternate approach to forming polymers by ring opening of 2-oxazolines involves the 2-mercaptoalkyl-2-oxazoline LIV, which polymerizes to LVII on heating [Gunatillake

et al., 1987] (Eq. 7-91). The reaction occurs through the zwitterion intermediate LV formed by proton transfer from sulfur to nitrogen. This reaction is a step polymerization of the zwitterion (an AB reactant). The zwitterion reacts with itself through nucleophilic attack of S on

(8.27)

7-91

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where C is an arbitrary constant. Now notice that for high-enough viscosity such that 'Y /m l/T, the exponential in the solution above will be negligible in any observable time interval. Integrating once more, Langevin then arrived at the following result: (8.28) This is the same result that one obtains starting with the diffusion equation (8.20), provided that D = kT / 'Y. So Langevin determined Einstein's diffusion coefficient in terms of the temperature, the coefficient of viscous friction, and Boltzmann's constant.

Type a name for the table. Click OK. Access lists the table among the database objects in the Navigation pane.

the oxazolinium ring to break the C bond and form a propagating zwitterion (LVI). Pro O pagation continues in the same way to form the polymer LVII. 2-Carboxyalkyl-2-oxazolines polymerize in a similar manner with nucleophilic attack of carboxylate anion on the oxazolinium ring [Gunatillake et al., 1988].

You can often get more insight by deriving a well-known result in a different way. Let us reflect a bit more about Langevin's approach. What happens if we use the assumption of quite high viscosity b /m l/T) right from the beginning Then neglecting m ~x/ dt 2 compared with 'Y dx/ dt, instead of (8.22) we can write

7-7 SULFUR HETEROCYCLICS The 3- and 4-membered cyclic sul des, referred to as thiiranes (also episul des) and thietanes, respectively, are easily polymerized by both cationic and anionic initiators, such as

dx dt =F,

7-92

(8.29)

the polymerization of ethylene sul de to poly(ethylene sul de) [IUPAC: poly(sulfanediylethylene)] [Aida et al., 1990; Boileau, 1989; Boucard et al., 2001; Goethals, 1989a,b; Kubisa, 1996; Sigwalt and Spassky, 1984]. Polymerization is more facile than with the corresponding cyclic ethers because of the more polarizable carbon sulfur bond. This also explains the polymerization of the thietanes by anionic initiators. However, cyclic sul des are less strained than their oxygen analogs because of the larger size of the sulfur atom, and the 5-membered ring tholane (tetrahydrothiophene), unlike tetrahydrofuran, does not undergo polymerization. There are no reported polymerizations of larger-sized cyclic sul des. By analogy to the cyclic ethers, the propagating species in cyclic sul de polymerization are considered to be the cyclic sulfonium (LVIII) and sul de anion (LIX) for cationic and anionic polymerization, respectively.

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Convert PDF to Word Using C# - C# Corner
Jul 13, 2015 · Convert PDF to Word Using C# The first step will be to get the PdfBox package using the Nuget Package Manager. Now, import the following DLLs into your .cs file: The third step will be to install the DocX NuGet Package from the NuGet Package Manager: Let's read a PDF file and try to get the text from it.












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