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lms can automatically possess the noncentral symmetric alignment, and the thin lms can show the signi cant second-order nonlinear optical (NLO) effect without electric eld poling The electrostatic layer-by-layer lms containing azo chromophores can also show photoresponsive behavior related with the photoisomerization (Wu et al, 2001; Dante et al, 1999) The block copolymer containing mesogenic azobenzene units in one of the blocks has been developed (Morikawa et al, 2006) The polymer can form thin lms with well-organized cylinder structures and photoinduced alignment properties Amphiphilic azo block copolymers have been prepared by ATRP, and light-responsive micellar aggregates have been obtained (Wang et al, 2004) Other recent progresses in the self-assembly of azo polymers can be seen in other chapters of this book This chapter reviews some recent research progresses concerning the colloidal spheres constructed from the polydispersed amphiphilic azo polymers.



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In contrast to the amphiphilic block copolymers being reviewed in s 6 and 7, the polymers discussed in this chapter are polydispersed amphiphilic azo homopolymers and random copolymers The polymers can be prepared through some relatively simple methods and are easily available from many resources The polymers can form uniform colloid spheres in selective solvent through selfassembling process The colloidal spheres can form ordered two-dimensional (2-D) arrays through vertical deposition, and the 2-D arrays can transform to ordered porous lms through in situ structure inversion In certain sense, these processes can well disclose the essence of self-assembly in which not only components spontaneously form order aggregates but also order can be produced from disorder Such self-assembled structures can be expected to show photoresponsive properties related to both the azo chromophores and the architectures at and beyond molecular level.





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In our discussion above, we have only touched on a small and simple subset of ASN1 Resources for learning more about ASN1 include the ASN1 standards document [ISO 1987, ISOX680], Philipp Hoschka's ASN1 homepage [Hoschka 1997], and [Larmouth 1996]

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Among them, photoinduced deformations observed on the colloidal sphere is one representative of such properties In s 3 and 4, light-induced bending of azo polymer lms has been reviewed by Yu and Ikeda, and azo polymer surface patterning through photoinduced mass migration has been reviewed by Yager and Barrett The photoinduced elongation observed on the colloids can be considered as another type of photoinduced motion effects..

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[Hoschka 1997] P Hoschka, "ASN1 homepage," http://www-sopinriafr/rodeo/personnel/hoschka/asn1 html [ISO 1987] Information processing systems - Open Systems Interconnection - Specification of Abstract Syntax Notation One (ASN1), International Organization for Standardization International Standard 8824, (December, 1987) [ISO X680] X680 : ITU-T Recommendation X680 (1997) | ISO/IEC 8824-1:1998, Information Technology - Abstract Syntax Notation One (ASN1): Specification of Basic Notation [Larmouth 1996] J Larmouth, "Understanding OSI," International Thomson Computer Press 1996 8 of this book deals with ASN1 and is available on-line at http://wwwsalfordacuk/iti/books/ osi/allhtml#head8

Generally, polydispersed amphiphilic azo homopolymers and random copolymers can be prepared through some relatively simple methods. One of the most feasible methods to prepare these polymers is through post-polymerization functionalization. In these synthetic routes, the azo chromophores are incorporated into the polymeric chains through some highly ef cient reactions of precursor polymers. Such reaction schemes can show some obvious advantages. As azo groups are inhibitors of radical polymerization, the polymerization of monomers containing azo chromophores could hardly produce a polymer with high molecular weight. The precursor polymers with high molecular weight can be obtained through radical polymerization. Through postpolymerization reaction scheme,

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azo polymers with high molecular weight can be obtained Moreover, because azo chromophores are sensitive to some chemical reactions, side reactions could occur during the polymerization of azo monomers Through postpolymerization reaction scheme, the functional groups are introduced at the last step of the polymer preparation, where azo chromophores will not be exposed to the detrimental environments such as free radical and high temperature However, postpolymerization reactions should have high reaction yield, otherwise azo polymers cannot possess the high degree of functionalization (DF) This could be one of the main limitations of the postpolymerization reaction scheme As typical examples, the polydispersed amphiphilic azo homopolymers and random copolymers can be obtained through postpolymerization azo coupling reaction (Wang et al, 1998, 1997b) and Schotten Baumann reaction (Wu et al, 2001) In the former, precusor polymers containing alilino moieties are prepared, which can be epoxy-based polymers, polyacrylates, and polyimides among others.

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