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The relative contribution of free ions to the overall propagation increases for lower acid concentrations There is app considerable error if the kp value is simply taken to be kp (as is often done since K is typi cally unknown and one cannot make the appropriate corrections) The ratio kp =kp is prob ably in the range 5 20 for most systems The calculated kp value is high by a factor of 15 for app kp =kp 5 One can safely equate kp with kp only for systems where C=K 103 104 or larger This can be done by using higher concentrations of tri ic acid as long as there are no solubility problems or the reaction rates are not excessively high For most of the systems reported in the literature, C=K is not known very often, neither K nor C is known.



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14We take a and b as real, of course, with a positive and greater than b, as in (4.104) and (4.105).





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For two-component initiator coinitiator systems, C is usually taken to be the initiator concentration [YZ] when the coinitiator is in excess or the coinitiator concentration [I] when the initiator is in excess C may be lower than [YZ] or [I] due to association; that is, only a fraction of [YZ] or [I] may be active in polymerization This may also be the case for one-component initiators such as tri ic acid It would be prudent to determine the actual value of C in any polymerization system usually a dif cult task and seldom achieved Experimental dif culties have also limited our knowledge of K values, which are obtained most directly from conductivity measurements or, indirectly, from kinetic data A comparison of polymerization in the absence and presence of a common ion salt (eg.

Figure 4.3 An ellipse rotated by (J. The projections on the x and y axes are denoted by ~x and ~y, respectively.

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, tetran-butylammonium tri ate for the tri ic acid initiated polymerization) is useful for ascertaining whether signi cant amounts of free ions are present in a reaction system Polymerizations initiated by ionizing radiation or stable carbocation salts such as trityl or tropylium hexachloroantimonate are useful for evaluating the free-ion propagation rate constant Ionizing radiation yields free ions (in the absence of ion pairs) whose concentrations.

As you can see, these equations are equivalent to (4.102) and (4.103). This sort of classical behavior of the quadrature variances of right-hand-side eigenstates of bJ1.,v is not a general rule. In fact, for an arbitrary quantum state, a simple calculation reveals that the rotated quadratures (~al(0)2) and (~a2(0)2) are related to the "old" ones, ~ad2) and ~a.)2), by

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TABLE 5-1 Kinetic Parameters in CF3 SO3 H Polymerization of Styrene at 20 C in ClCH2 CH2 Cla Parameter [Styrene] [CF3 SO3 H] ki Kd kp kp kts kt ktr;M

Osin 0,

Value 0:27 0:40 M 3:8 7:1 10 3 M 10 23 L mol 1 s 1 4:2 10 7 mol L 1 1:2 106 L mol 1 s 1 1:0 105 L mol 1 s 1 170 280 s 1 < 0:01kts 1 4 103 L mol 1 s 1

(4.112)

Data from Kunitake and Takarabe [1979].

(4.113)

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