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XL {(a IPa, (t) Ib) (b IPa, (t)1 a)

To include noncontiguous cells and ranges In a chart, select the first cell or range and then press and hold while selecting additional cells and ranges.



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The various forms of the copolymerization equation (Eqs. 6-12 and 6-15) give the instantaneous copolymer composition the composition of the copolymer formed from a particular feed composition at very low conversion (approximately <5%) such that the composition of the comonomer feed is relatively unchanged from its initial value. For all copolymerizations except azeotropic copolymerizations the comonomer feed and copolymer compositions are different. The comonomer feed changes in composition as one of the monomers preferentially enters the copolymer. Thus there is a drift in the comonomer composition toward the less reactive monomer as the degree of conversion increases. This results in a similar variation of copolymer composition with conversion. In order to determine the instantaneous copolymer composition as a function of conversion for any given comonomer feed, one must resort to an integrated form of the copolymerization equation. Direct integration of Eq. 6-12 for this purpose has resulted in solutions of varying utility [Kruse, 1967; Mayo and Lewis, 1944; Van der Meer et al., 1978; Wall, 1944]. A useful method for analyzing copolymer composition as a function of conversion is that developed by Skeist [1946]. Consider a system initially containing a total of M moles of the two monomers and in which the copolymer formed is richer in monomer M1 that is the feed (i.e., F1 > f1 ). When dM moles of monomers have been copolymerized, the polymer will contain F1 dM moles of monomer 1 and the feed will contain M dM f1 df1 moles of monomer 1. A material balance for monomer 1 requires that the moles of M1 copolymerized equal the difference in the moles of M1 in the feed before and after reaction, or





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Mf1 M dM f1 df1 F1 dM 6-32

- (a IPa, (t)1 b) (b IPa, (t)1 a) eiwabT }

Equation 6-32 can be rearranged (neglecting the df1 dM term, which is small) and converted to the integral form

(6.29)

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Radiation-initiated polymerization has achieved some commercial success. The most frequently used radiation is electrons, the technology is called electron-beam (EB) technology. Electrons as well as other ionizing radiations (except for a-particles) have a signi cant advantage over UV and visible radiation. The depth of penetration is much greater with less attenuation for ionizing radiations than for UV and visible. There are several areas of application for EB technology [Fouassier and Rabek, 1993]. Coatings and other thin reactions systems (involving mostly polymerization with crosslinking Sec. 6-6a) are an area of application where EB competes directly against UV and visible light. EB is not used to the same extent as UV and visible because of the higher overall equipment costs and the perception that working with ionizing radiations is risky from a health safety viewpoint. Other EB uses include the crosslinking of wire and cable insulation and packaging lms (Sec. 9-2c). EB is the technology of choice in microelectronics fabrication.

x { (a IPaAt) I b) (b IPa, (t) I a) - (a IPa, (t)1 b) (b IPaAt) I a) },

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