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until eventually large-sized polymer molecules have been formed. The characteristic of step polymerization that distinguishes it from chain polymerization is that reaction occurs between any of the different-sized species present in the reaction system. The situation is quite different in chain polymerization where an initiator is used to produce an initiator species R* with a reactive center. The reactive center may be either a free radical, cation, or anion. Polymerization occurs by the propagation of the reactive center by the successive additions of large numbers of monomer molecules in a chain reaction. The distinguishing characteristic of chain polymerization is that polymer growth takes place by monomer reacting only with the reactive center. Monomer does not react with monomer and the different-sized species such as dimer, trimer, tetramer, and n-mer do not react with each other. By far the most common example of chain polymerization is that of vinyl monomers. The process can be depicted as



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Equations (9.50) and (9.54)-(9.56) agree with Barnett and Radmore's expressions [37] for 'coupling strength 12:

R CH2 C CH2 C*

(9.57)

H CH2 C*





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More from SautinSoft Team
More from SautinSoft Team

So we have derived from first principles the phenomenological Gardiner-Collett Hamiltonian (91), have demonstrated that it holds only for high-Q cavities, and have found the reason why it breaks down away from the high-Q regime Moreover, we have derived an explicit expression for the coupling strength within our simple one-dimensional model Let us look into what this expression tells us As the cavity photons can only escape to the external continuum of modes, there is really just a single reservoir (this external continuum) for all cavity modes In quantum optics, however, it is often tacitly assumed [261] that each mode is coupled to an independent reservoir The explicit expression (957) for the coupling strength that we have found shows how this effective independent reservoir behavior emerges from a single reservoir in the high-Q regime The sinc function in (9.

1-9

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57) splits the continuum of external modes into a collection of smaller reservoirs, each having a finite frequency width and coupled to a single-cavity mode Their independency arises from the smallness of the overlap of a given cavity mode with neighboring cavity resonances in the high-Q regime (see Figure 93) Grangier and Poizat [247, 248] have shown that the breakdown of the independent reservoir assumption is essential for the appearance of excess quantum noise in lasers This is a curious phenomenon first found in gain-guided semiconductor lasers by Petermann [491], where a laser has a linewidth larger than the usual SchawlowTownes Iinewidth, as if there were more than one spontaneous emission noise photon per mode Later, Siegman developed a semiclassical theory [561, 562], where excess noise emerges as a consequence of mode nonorthogonality.

Access databases store all data in tables. A table is a list of information organised into columns and rows that intersect to form cells for holding data. A table might list the names, addresses, phone numbers, company names, titles and e-mail addresses of your clients. Each row in a table is considered a record. You can use columns to hold fields, which are the individual units of information contained within a record. If you need to add a table to a database, you can easily do so. All table objects that you create appear listed in the Navigation pane; simply double-click a table object to open it.

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