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The azobenzene-containing polymers (azo polymers for short) can show a variety of unique photoresponsive properties triggered by the photoisomerization (Natansohn and Rochon, 2002; Delaire and Nakatani, 2000; Xie et al, 1993) The polymeric materials are expected for the applications in areas such as data storage, optical switching, sensors, and actuators (Yager and Barrett, 2001; Kawata and Kawata, 2000; Xie et al, 1993) Many types of the azo polymers have been designed and synthesized, which include side-chain, main-chain, dendritic azo polymers, and block copolymers (Lambeth and Moore, 2007; Natansohn and Rochon, 2002; Tian et al, 2002; Junge and McGrath, 1999; Archut et al, 1998; Kumar and Neckers, 1989) The azo polymers have been prepared by radical polymerization, step-growth polycondensation, atomic transfer radical polymerization (ATRP), and ring-opening metathesis polymerization (ROMP) among others.



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Table 84-1 shows a few of the ASN1 defined data types Recall that we encountered the INTEGER, OCTET STRING and OBJECT IDENTIFIER data types in our earlier study of the SMI Since our goal here is (mercifully) not to provide a complete introduction to ASN1, we refer the reader to the standards or to the printed and on-line book [Larmouth 1996] for a description of ASN1 types and constructors such as SEQUENCE and SET that allow for the definition of more structures





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The polymeric backbones not only perform as a good medium with transparent and easy-processable properties but also play an important role in transferring or coordinating the photoisomerization effect of azo chromophores For azo polymers, light irradiation can cause photoresponsive variations such as phase transition (Ikeda et al, 1990), photoinduced chromophore orientation (Todorov et al, 1984), light-driven thin- lm contraction and bending (Li et al, 2003; Yu et al, 2003; Finkelmann et al, 2001), and surface relief grating (SRG) formation (Kim et al, 1995; Rochon et al, 1995) The last but not the least of importance, polymeric chains are able to undergo different self-assembling processes The structures and photoresponsive properties of the azobenzene-containing materials can be dramatically enriched through the self-assembling approaches.

Description value is "true" or "false" can be arbitrarily large list of one or more bits list of one or more bytes no value floating point Table 84-1: selected ASN1 Data Types

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Self-assembly generally refers to a process in which components, either separate or linked, spontaneously form order aggregates (Whitesides and Boncheva, 2002; Whitesides and Grzybowski, 2002) Self-assembly has been extensively explored to develop a variety of well-de ned structures through bottom-up approaches (Forster and Plantenberg, 2002; Philp and Stoddart, 1996) Azo polymers with specially designed functional groups or chain structures can undergo different types of selfassembly Multilayer thin lms composed of azo polyelectrolytes have been obtained through sequential electrostatic layer-by-layer self-assembly (Laschewsky et al, 1997; Lvov et al, 1997; Wang et al, 1997a) The azo chromophores in the.

file:///D|/Downloads/Livros/computa o/Computer%20NetDown%20Approach%20Featuring%20the%20Internet/asn1htm (4 of 7)20/11/2004 15:53:16

development the F136 produced by General Electric in conjunction with Rolls-Royce had its funding reinstated. Some of the requirements of the four sponsoring Services appear to be diametrically opposing in terms of achieving a nal solution and present severe challenges. Nevertheless, if a high degree of commonality can be maintained between the competing variants and/or requirements then the US military authorities will have achieved a degree of standardisation which will doubtless yield signi cant bene ts of scale: both to the operational Services and the taxpayer on both sides of the Atlantic

In addition to providing a data description language, ASN1 also provides Basic Encoding Rules (BER) that specify how instances of objects that have been defined using the ASN1 data description language are to be sent over the network The BER adopts a so-called TLV (Type, Length, Value) approach to encoding data for transmission For each data item to be sent, the data type, the length of the data item, and then the actual value of the data item are sent, in that order With this simple convention, the received data is essentially self identifying Figure 844 shows how the two data items in our simple C-language example above would be sent In this example, the sender wants to send the letter 'a' followed by the value 259 decimal (which equals 00000001 00000011 in binary, or a byte value of 1 followed by a byte value of 3) assuming big-endian order The first byte in the transmitted stream has the value 4, indicating that the type of the following data item is an OCTET STRING; this is the 'T' in the TLV encoding The second byte in the stream contains the length of the OCTET STRING, in this case 1 The third byte in the transmitted stream begins (and ends) the OCTET STRING of length one; it contains the ASCII representation of the letter 'a' The T, L, and V values of the next data item are 2 (the INTEGER type tag value), 2 (ie, an Integer of length 2 bytes), and the two-byte big-endian representation of the value 259 decimal)

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