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The incorporation of azobenzene into small amphiphilic molecules to make photosensitive surfactants has been much studied (Eastoe and Vespertinas, 2005; Lee et al., 2004; Shang et al., 2003; Orihara et al., 2001; Kang et al., 2000; Einaga et al., 1999; Sakai et al., 1999; Shin and Abbott, 1999; Yang et al., 1995; Shinkai et al., 1982). The main interest of such surfactants is to cause property changes of aqueous solutions in response to illumination as a result of the trans cis photoisomerization of the chromophore. Not surprisingly, many light-induced property changes are related to a disruption of micelles self-associated by azobenzene surfactant molecules (Lee et al., 2004; Shang et al., 2003; Kang et al., 2000; Shin and Abbott, 1999; Yang et al., 1995). For example, using 4,4u-bis (trimethylammoniumhexyloxy) azobenzene bromide, Shin and Abbot observed a signi cant decrease in dynamic surface tension upon illumination of UV light. They attributed this to a decrease in the number of micelles in solution that increases the rate of mass transport of surfactant molecules to the interface. In another study, Lee et al., demonstrated that the solution viscosity and gelation behavior of mixtures of azobenzene trimethylammonium bromide and a hydrophobically modi ed polymer could be reversibly controlled with UV and visible light. A light-induced dissolution of micelles formed by trans-azobenzene surfactants with the hydrophobic side groups of the polymer, acting as cross-links of polymer chains, was believed to be at the origin of the phenomenon. Generally, azobenzenecontaining surfactants display a higher critical micelle concentration (cmc) with



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application) If Host A initiates the Telnet session (so that a user at Host A is logging onto Host B), then Host A runs the client side of the application and Host B runs the server side On the other hand, if Host B initiates the Telnet session, then Host B runs the client side of the application FTP, used for transferring files between two hosts, provides another example When an FTP session exists between two hosts, then either host can transfer a file to the other host during the session However, as is the case for almost all network applications, the host that initiates the session is labeled the client Furthermore, a host can actually act as both a client and a server at the same time for a given application For example, a mail server host runs the client side of SMTP (for sending mail) as well as the server side of SMTP (for receiving mail)





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Smart Light Responsive Materials. Edited by Yue Zhao and Tomiki Ikeda Copyright r 2009 John Wiley & Sons, Inc.

As noted above, an application involves two processes in two different hosts communicating with each other over a network (Actually, a multicast application can involve communication among more than two hosts We shall address this issue in 4) The two processes communicate with each other by sending and receiving messages through their sockets A process's socket can be thought of as the process's door: a process sends messages into, and receives message from, the network through its socket When a process wants to send a message to another process on another host, it shoves the message out its door The process assumes that there is a transportation infrastructure on the other side of the door that will transport the message to the door of the destination process

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Figure 21-1: Application processes, sockets, and the underlying transport protocol Figure 21-1 illustrates socket communication between two processes that communicate over the Internet (The figure assumes that the underlying transport protocol is TCP, although the UDP protocol could be used as well in the Internet) As shown in this figure, a socket is the interface between the application layer and the transport layer within a host It is also referred to as the API (application programmers

azobenzene moieties in the cis form (upon UV illumination) (Lee et al, 2004; Orihara et al, 2001; Shin and Abbott, 1999; Yang et al, 1995) Among the rare reports focused on the photoinduced disruption of micellar aggregates of azobenzene surfactants, most noticeable works came from Sakai s group (Orihara et al, 2001; Sakai et al, 1999) They showed direct evidence that micelles and vesicles formed in aqueous solution of 4-butylazobenzene-4u-(oxyethyl)trimethylammonium bromide (or its mixtures with another surfactant) could be reversibly disrupted by alternating UV and visible light irradiation These systems allowed them to demonstrate the possibility of photocontrolling the release of either hydrophobic or hydrophilic compounds solubilized by micelles and vesicles, respectively Another interesting study was reported by Hashimoto s group (Einaga et al, 1999).

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