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When a network application wants to communicate with another application across the network, it must first prepare the data in the specific format defined by the protocol to be used by the receiving application. A specific protocol is used so that the receiving application will know how to interpret the data it receives. For example, in the case of a world wide web (WWW) request, the message consists of two parts, the message header and the body, as shown in Figure 1.9. The message header contains the sender s and receiver s addresses, as well as other information such as the urgency of the message and the nature of the message body. The format of the header and the nature of the addressing are defined by the application protocol. In the case of a WWW request the protocol is the hypertext transfer protocol (hTTP). In addition to defining the format of the message, the protocol also specifies how the applications are expected to interact with each other, including the exchange of commands and the expected responses.

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The presence of a concentration gradient of electroactive substances at the phase boundary between the electrode and the solution or between two electrolytes, the presence of an electric field and, finally, the effect of mechanical forces all lead to transport processes, described in 2 It should be pointed out that investigations in electrochemical kinetics are usually carried out with solutions containing an excess of indifferent electrolyte compared to the electroactive substance, to exclude the effect of migration The rule for the equivalence between the material flux of the charged species and the electric current (Eq 2314) is a general formulation of the Faraday law In its classical form, this rule is connected with a special case, ie material flux through the electrode-solution interface In this special case the Faraday law deals with equivalence between the material yield in an electrode reaction and the charge passed: 1.

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Figure 1.9 A WWW application creates a message that includes the sender and recipient information in the message header and the contents of the message in the message body.

The amount of substance converted in the electrolysis is proportional to the charge passed 2 The amounts of various substances converted by a given charge correspond to the ratio of the chemical equivalents of these substances The electric current connected with chemical conversion is termed the faradaic current in contrast to the non-faradaic current required to charge the electrical double layer The equation for the electrode reaction is formulated similarly to that for the half-cell reaction (Section 314); for the cathodic reaction, the electrons are placed on the left-hand side of the equation and, for the anodic reaction, on the right-hand side Consider the electrode reaction of metal deposition: Mn+ + ne-^M (512) If current / flows through the solution for time ty then the charge It is passed, corresponding to a transfer of It/F moles of electrons.

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TCP treats all application data as a simple byte stream, including both the message header and the message body. TCP accepts the application s data and breaks it into segments for transmission across the network as required. To accomplish this reliable transfer, TCP packages the application data with a TCP header. On the receiving end of the connection, the TCP protocol removes the TCP header and reconstructs the application data stream exactly as it was received from the application on the sender s side of the network. In other words, TCP simply takes the data given to it by the upper layer application, and passes it to the upper layer application at the other end without trying to interpret the contents. Any protocol-specific formatting of the data is up to the upper layers. As shown in Figure 1.10, the TCP and UDP headers carry source and destination addresses that identify the sending and recipient applications because a single host system may support multiple applications, as mentioned previously. These addresses are known as port numbers. Some port numbers are considered well known and should become familiar to you, such as port 80 for hTTP, port 21 for FTP, port 25 for Simple Mail Transfer Protocol (SMTP) and port 23 for Telnet. To transmit its segments of data across the network, TCP uses the services of the IP layer.

If the relative atomic mass of the metal is M, then a total amount of (513,.

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