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and 4 all need to communicate with each other, their respective providers could fulfill this need by using a Tier 1 provider network or IXP as a transit network. In the next section, we take a closer look at service providers and their functions.



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The continuum theory is based on the concept of a continuous change of the parameters of the water molecule with temperature Recently, however, theories based on a model of a mixture have become more popular It is assumed that liquid water is a mixture of structurally different species with various densities With increasing temperature, there is a decrease in the number of low-density species, compensated by the usual thermal expansion of liquids, leading to the formation of the well-known maximum on the temperature dependence of the density of water (0999973 g cm"3 at 398 C) There are various theories on the structure of these species and their size Some authors have assumed the presence of monomers and oligomers up to pentamers, with the open structure of ice I, while others deny the presence of monomers.





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Other authors assume the presence of the structure of ice I with loosely arranged six-membered rings and of structures similar to that of ice III with tightly packed rings Most often, it is assumed that the structure.

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15 consists of clusters of the ice I type, with various degrees of polymerization, with the maximum of the cluster size distribution in the region of oligomers and with a low concentration of large species The following simple concept is sufficient for our purposes To a given water molecule, two further water molecules can become bonded fairly strongly through their negative 'ends' by electrostatic forces in the direction of the O H bond (hydrogen bonds) Additional two water molecules are then bound to the original molecule through their positive 'ends' In the sterically most favourable position these two molecules occupy the positions of the remaining two apices of a tetrahedron whose first two apices lie in the direction of the O H bonds This process results in a tetrahedral structure, the effective charge distribution in the water molecule being quadrupolar.

When the Internet was in its early commercial days, traditional ISPs provided access to basic services such as email and Web surfing via a modem dial-up The connections were low speed with a theoretical limit of 56 Kbps at the peak of modem technology Achieving the peak rate was rare, with actual speeds in the 28-Kbps to 36-Kbps range The nature of the low-speed connections severely limited the range of services that ISPs could offer Typical services consisted entirely of simple text-based web pages, email, and chatrooms Additionally, the modem line often had to be shared with the home voice phone, so connectivity was limited to only those times when a connection was required This paradigm changed dramatically as consumers began to have access to high-speed services such as DSL, and ISPs evolved to provide many additional services to customers.

In the solid state, each water molecule has four nearest neighbours (Fig 13) This is a very 'open' arrangement that collapses partially on melting (the density of water is larger than that of ice) Thus, liquid water retains clusters of molecules with the structure of ice that constantly collapse and reform About half of the water molecules are present in these clusters at a given instant X-ray structural analysis indicates that, in the liquid state, each water molecule has an average of 45 nearest neighbours This is far less than would correspond to the most closely packed arrangement (12 nearest neighbours) The existence of a certain degree of ordering in liquid water can also explain the unusually high value of the heat of vaporization, entropy of vaporization, boiling point, and dielectric constant of water compared with similar simple substances, such as hydrogen sulphide, hydrogen fluoride, and ammonia.

Modern ISPs can be content providers or peer with several other content providers to provide their users with a myriad of services mainly categorized by voice, video, and data applications The newer ISPs now compete with the traditional cable, satellite, and telecom providers The bundling of these three major services that were offered as individual services in the past is referred to as Triple Play In contrast, some of the cable and satellite providers are offering Internet services such as voice and data and also are able to peer with other ISPs and content providers and, in turn, compete with the telecom providers and other ISPs Deregulation has also allowed companies who traditionally were able to offer only single services such as voice or cable, to offer new services in a wide-open, competitive services marketplace A major motivation behind the bundling of traditionally offered individual services is cost reduction.

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