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*B:PE1# show port 1/1/1 ======================================================== Ethernet Interface ======================================================== Description : 10/100/Gig Ethernet SFP Interface : 1/1/1 Oper Speed : 1 Gbps Link-level : Ethernet Config Speed : 1 Gbps Admin State : up Oper Duplex : full Oper State : up Config Duplex : full Physical Link : Yes MTU : 1514 [... 4 lines of output omitted ...]

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The basic condition for electron transfer in cathodic processes (reduction) to an electroactive substance is that this substance (Ox) be an electron acceptor It must thus have an unoccupied energy level that can accept an electron from the electrode The corresponding donor energy level in the electrode must have approximately the same energy as the unoccupied level in the substance Ox On the other hand, in oxidation processes, the electroactive substance Red must have the character of an electron donor It must contain an occupied level with energy corresponding to that of some unoccupied level in the electrode Oxidation occurs through transfer of electrons from the electroactive substance to the electrode or through the transfer of holes from the electrode to the electroactive substance Thus, an electrode redox reaction occurs according to the scheme Red + unoccupied level * Ox + occupied level (51.

Configured Mode : access Encap Type Dot1Q Ethertype : 0x8100 QinQ Ethertype PBB Ethertype : 0x88e7 [... Additional output omitted ...] *B:PE1#

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1) This situation is depicted in Fig 51 The occupied level in the substance Red2 has an energy corresponding to the unoccupied level in the electrode Thus, oxidation can occur (either through the transfer of an electron e~ to the electrode or of a hole h + from the electrode) On the other hand, the unoccupied level in the substance Oxx has too high an energy, so that it does not correspond to any of the occupied levels in the electrode as all these levels lie below the Fermi level F, while the energy of the unoccupied level of the substance Oxt is far above this level Reduction can thus not occur The situation is the opposite for the substances Red2 and Ox2 As was demonstrated in Section 312, the energy of the Fermi level is identical with the electrochemical potential of an electron in the metal.

A VPLS is a Layer 2 service that connects multiple sites in a single LAN. It s like creating a virtual switch from a network of Service Routers. In this lab, we will configure the actual VPLS across the PE nodes as shown in Figure 11.16. The PE devices will connect to each other in a full mesh topology using mesh-type SDPs. The CE devices will be configured to use the same subnet (i.e., addresses from a single LAN). The operation of the VPLS will be demonstrated using ping, traceroute, and (optionally) OSPF.

A change in the inner potential of the electrode phase by A(p (attained by changing the potential difference of an external voltage source by AE =.

Note that after the service reference topology has been configured, adding additional services from edge-to-edge does not require any further modification of the supporting infrastructure.

Some values of association constants are listed in Table 1.1. The dependence of ion-pairing on the dielectric constant is illustrated in the following example. The formation of K + CP ion pairs in aqueous KC1 solutions has not been demonstrated. In methanol (D = 32.6), for KC1,

Select OK to mark each image to print one print of each Clear All Selections This setting allows you to deselect all images and quantities marked for printing There is no undo for this selection once you unmark images Print Settings Choosing this selection opens the Print Settings menu and allows you to control several printing options:.

24 Table 1.1 Values of log K.ass for some ion pairs in aqueous solutions at 25 C (according to C. W. Davies), where indicates that ion pair formation could not be proved IT OH F" -0.08 0.6 3.1 3.9 Na+ -0.7 -0.6 0.7 0.6 1.16 2.4 2.7 K+ -0.2 1.0 0.9 2.3 2.7 Ag+ 2.3 0.4 3.2 4.4 -0.2 1.3 8.8 TT 0.8 0.1 0.5 1.0 0.3 1.4 1.9 Ca 2+ Cu 2+ 1.30 1.0 0.28 2.28 1.95 3.46 6.8 8.1 1.23 0.4 0.0 2.36 Fe 3+ 12.0 6.04 1.5 0.60 1.0

Figure 11.16: Customer equipment connects to the Provider Edge via a SAP. To the customer, the SAP in a VPLS behaves identically to a port on an Ethernet switch.

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