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251 (this process can occur through other mechanisms; see Section 5.7.1). In the second case, the reduction C6H5CHO + H + - C6H5C+HOH C6H5C+HOH + e ^ C6H5CHOH 2C6H5CHOH-^ C6H5CHOH.CHOHC6H5 occurs at the mercury electrode under suitable conditions (pH, potential). The deposition of cadmium from its cyanide complex at a mercury electrode is analogous. A solution containing cyanide ions in a concentration of 1 mol dm"3 contains practically only the Cd(CN)42~ complex. This complex cannot participate directly in the electrode reaction and thus the Cd(CN)2 complex enters the electrode reaction in a given potential range; the equilibrium concentration of this complex in solution is small. The reaction scheme can then be written as Cd(CN)42" ^ Cd(CN)3~ + CN" Cd(CN)2 + 2CN~ Cd(CN)2 + 2 e ^ Cd(Hg) + 2CN~ (5.1.9) (5.1.8)

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For this exercise, we will treat CE1 and Device4 as traditional routers. Their interfaces will use addresses from a common subnet, even though they are on opposite sides of a service (which may span a city, a continent, or the globe). The VPLS service will join these two devices in the same way an Ethernet switch would join them. The minimum requirements for Device4 are that it be capable of sending and responding to pings. we will, however, walk through the full configuration in case Device4 is an Alcatel-Lucent 7750/7450 device. Determine whether you have the ability to set the IP address of Device4. Set it to 192.168.0.4 if you can. If not, carefully note the address and subnet mask of the interface connected to PE2. You will need to adapt the examples below to give PE1 a compatible IP address and mask so that it is part of the same subnet as PE2. 1. Reconfigure the interface on CE1 that connects to PE1. It should now use an address of 192.168.0.1/24. (we will leave the name of the interface the same, even though a new name like toISP or toVPLS would be more appropriate to this exercise.)

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It is obvious that the electrode process in general is more complicated than would appear from simple overall schemes of electrode processes. It often happens that the substances that are the initial components in the overall reaction are not those that participate in the actual electrode reaction; the latter are rather different substances in chemical equilibrium with the initial components. The case where the overall reaction involves several electrode reactions is even more general. An example is the reaction of quinone (Q) at a platinum electrode. This process occurs at pH < 5 according to the scheme

*A:CE1# configure router *A:CE1>config>router# interface toPE1 *A:CE1>config>router>if# address 192.168.0.1/24 *A:CE1>config>router>if# exit *A:CE1>config>router# exit *A:CE1#

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Two chemical equilibria participate in this process and, in addition, stepwise charge transfer reactions occur. The product of the first electrode reaction undergoes a further electrode reaction. Electrochemical kinetics is part of general chemical kinetics and has a similar purpose: to determine the mechanism of the electrode process and quantitatively describe its time dependence. Mostly the study involves several stages. Firstly it is necessary to determine the reaction path, i.e. to determine the mechanism of the actual electrode reaction (for more detail, see Section 5.3.1), and the partial steps forming the overall electrode

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2. Assuming that Device4 is an Alcatel-Lucent 7750/7450 device, configure the basic router settings and the interface to PE2. If Device4 is some other device and you are able to set the IP address and subnet mask, do so now.

process The next task involves finding the step that is the slowest and, therefore, controls the overall rate of the process, ie the current The other, faster steps are then not apparent as the appropriate equilibrium is established (eg in the chemical reaction or the electrode reaction) or because they are negligible (eg convective diffusion in connection with a very slow charge transfer reaction, where the concentration gradient formed is removed by stirring the solution) For more complex electrode mechanisms, it is useful to designate the individual steps by symbols: E for an electrode reaction and C for a chemical reaction Thus, the mechanisms of the process (517) are denoted as EC, of (519) as CE, of (518) as CEC and of (5110) as CECE.

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