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A typical Data Link frame contains a header, usually containing some type of address. The frame also often carries a trailer that contains some type of checksum to verify the integrity of the transmitted data. There are many types of technology used as network interfaces by IP, and they each have their own specific format and rules of operation. As noted earlier, the common characteristic is that the technologies are all capable of carrying IP datagrams. The addressing at this layer identifies the two endpoints of a data exchange to the data link protocol. For example, Figure 1.12 shows the addressing of an Ethernet frame. Some Point-to-Point Protocols such as PPP may not use addresses if there is only one possible destination for the data. After all, you don t need addressing when two network devices can only send information to each other. If it was not obvious from the preceding discussion, routers provide the critical traffic control of the IP datagrams across the Internet. Once the end-user s computer creates the packet and places it on the wire, its job is done until it receives a response. From the user s perspective, the information simply goes into a black box and gets sent to its destination, and a response is received. Behind the scenes, numerous, sometimes dozens, of routers reliably perform their duties accepting packets, examining the destination, looking up the next hop router for delivery, and forwarding the packet on its merry way. Along the way, the packet may cross Ethernet, ATM, Frame-Relay, PPP,



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See references on page 253 Delahay, P., Double Layer and Electrode Kinetics, John Wiley & Sons, New York, 1965. Parsons, R., Electrode reaction orders, charge transfer coefficients and rate constants. Extension of definitions and recommendations for publication of parameters. Pure AppL Chem., 52, 233 (1979). Tamamushi, R., Kinetic Parameters of Electrode Reactions of Metallic Compounds, Butterworths, London, 1975. Vlcek, A. A., Relation between electronic structure and polarographic behaviour of inorganic depolarizers. VII. Determination of activation energy of electrode processes. Coll. Czech. Chem. Comm., 24, 3538 (1959).

and carrier pigeon to reach its intended destination (OK, maybe not really carrier pigeon, but you get the idea). Figure 1.13 illustrates this concept.

(5.2.57)

Figure 1.12 The data link layer adds source and destination MAC addresses for forwarding on the local network segments.





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5.3 The Theory of Electron Transfer 5.3.1 The elementary step in electron transfer This part is concerned with discussion of the reaction mechanism in a narrower sense, i.e. the 'microscopic' elementary step in the electrode reaction, connected with the transfer of a single electron between the

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267 electrode and the oxidized or reduced form of the electroactive substance The possibility of adsorption interaction between the electrode and the electroactive substance is excluded The contemporary theory of chemical reactions attempts to describe similar microscopic steps on the basis of construction of the potential energy hypersurface of the reacting system if the applicability of the BornOppenheimer approximation can be assumed In this approximation, also called the adiabatic approximation, the nuclear motion of the atoms (forming the molecules of the reactants and products) is supposedly independent of the motion of the electrons forming the electron shells of these atoms The path of the reacting system across this hypersurface is termed the system trajectory An advantageous system trajectory passing through a minimum in the valley of the energies of the reactants and products and through a saddle point on the hypersurface is the reaction path of the system.

From these control screens, use the top, bottom, left, and right areas of the 4-Way Controller and the Quick Control dial to make your selections and press the Function/ Set button to accept all changes. The interface is elegant, the type and symbols are large and easy to see, and the 4-Way Controller button s response is fast and accurate. I must say I was very impressed with this new display on my rst outings with the G11, not only for its ability to quickly change exposure, shooting mode, image quality, and My Color settings but to be able to see a nice illuminated adjustable readout of those settings in the midst of a fast-paced shooting session.

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Obviously, construction of the potential energy hypersurface of the system encounters numerous difficulties and is possible only in the simplest case (reactions in the gaseous state) Thus, the discussion of elementary processes is often limited to discussion of energy profiles, based on a cross-section through the hypersurface along the estimated reaction pathway, where the resultant diagram, the reaction profile, describes only the dependence of the potential energy on the reaction coordinate The reaction coordinate indicates the change of a single space coordinate of the system during the reaction Attempts were made to quantitatively treat the elementary process in electrode reactions since the 1920s by J A V Butler (the transfer of a metal ion from the solution into a metal lattice) and by J Horiuti and M Polanyi (the reduction of the oxonium ion with formation of a hydrogen atom adsorbed on the electrode).

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