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2.3.2.11 Not All Cofactors Are Derived from Vitamins. It is worth emphasizing that not all cofactors are synthesized from a vitamin. For example, since tetrahydrobiopterin (BH4, Fig. 2-4B), the cofactor for phenylalanine hydroxylase and other enzymes that hydroxylate aromatic amino acids, is synthesized in the body from guanosine triphosphate (GTP), it is not a vitamin. Similarly, lipoic acid, which is one of several cofactors for the pyruvate dehydrogenase and a-ketoglutarate dehydrogenase complexes, is not a vitamin. It should also be noted that not all vitamins are precursors of cofactors. Indeed, vitamin K is the only one of the four fat-soluble vitamins that plays a direct catalytic role in an enzyme-catalyzed reaction in the body. Two other fat-soluble vitamins, retinol (vitamin A) and cholecalciferol (vitamin D), are actually precursors of hormones that regulate transcription of DNA, and thus gene expression. Retinol is also the precursor of 11-&-retinal, which is an important constituent of rhodopsin, the visual pigment of the eye. a-Tocopherol (vitamin E), the fourth fat-soluble vitamin, is an antioxidant. 2.3.3 Many Enzymes Utilize Metal Ions as Part of Their Catalytic Mechanisms

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where di, j is the distance value between pairs of observations; for example, d1,2 is the distance between the rst and second observation. The diagonal values are all zero distances since there is no distance between two identical observations. The distance matrix for the observations in Table 3.5, using the Gower distance (described in Section 3.3.4) over all variables, is: A B 6A 0 0:865 6 6 B 0:865 0 D 6 6 C 0:754 0:677 6 4 D 0:836 0:227 E 0:178 0:814 2 3 C D E 0:754 0:836 0:178 7 7 0:677 0:227 0:814 7 7 0 0:67 0:688 7 7 0:67 0 0:777 5 0:688 0:777 0

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No. of lines Name of system Emphasis improvement P (dB) (1) 3.1 2.0 Weighting factor W (dB) (2) 11.7 11.2 Emphasis improvement and weighting factor P + W (dB) 14.8 13.2

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In this lucid account, the intersecting play of economics, politics and education lead to a sequence of geographical decisions: emigration, return by the principal wage-earner, full return by both parents with the option of future re-migration, while leaving unresolved the location of the children following university graduation With a more specific question about the choice of Vancouver, given the decision to move to Canada, quality of life remained as the most common response, followed by the presence of a pre-existing network of friends and relatives, and even the Vancouver climate, more temperate than the rest of Canada (Table 31) These interviews were consistent with results from the federal government s Longitudinal Survey of Immigrants to Canada (LSIC) conducted at the same time (2001 02) The relevant LSIC sample comprised economic migrants from all countries, including business immigrants and also the much larger class of skilled workers.

Among the most important reasons for selecting their place of residence in Canada, the presence of family or friends was an abiding first choice, confirming the important role of social networks (and social capital) in steering immigrant site selection (Statistics Canada 2003b) In Toronto (and most other places) job prospects were in second rank, but in Vancouver the second attraction was climate and the third was lifestyle Educational opportunities followed, while job prospects in Vancouver were mentioned by only six percent of this sample of economic migrants, whom we would have expected to be highly attentive to the regional labour market Returning to Table 31 we see the same demotion of economic factors in the motives to move to Canada among the 90 Vancouver area entrepreneurs19 On the surface, this is an extraordinary outcome.

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