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We can relate the forward rate s rate of change parameters to the zero-coupon bond price process s rate of return parameters in the up and down states, respectively, as follows: (t , T ; st ) = and (t , T ; st ) = d (t , T ; st ) f (t + 1, T ; st d) = for t + 1 T d (t , T + 1; st ) f (t , T ; st ) u (t , T ; st ) f (t + 1, T ; st u) = for t + 1 T u (t , T + 1; st ) f (t , T ; st )



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5 ) it is necessary to discriminate between the rotational/vibrational and the transitional temperature, which some of the described techniques allow. Temperature is usually defined as a thermodynamic quantity arising from the macroscopic properties of a system which can be described by equations of state, such as the Ideal Gas Law. This must be distinguished from the atomistic definition, which deals with the population at different energy levels and which is the basis of the spectroscopic definition of temperature. In the case of JR and Raman spectroscopy, only the vibrational and the rotational states are of interest usually. According to the Boltzmann distribution law, the population of a distinct level of energy E, is proportional to

Scheme 5-23





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Open SQL Server Business Intelligence Development Studio (BIDS) from Start Programs Microsoft SQL Server 2008. Open an SSIS solution, select SSIS Import and Export Wizard from the Project menu or by right-clicking the SSIS Packages folder. Run DTSWizard.exe (C:\Program Files\Microsoft SQL Server\100\DTS\Binn) from the command prompt.

As was the case for the silylated molecules, FcP increased as the length of the chain increased, and again kc/kd was linearly proportional to m1/2/r 253 Although this is just the second experimental veri cation of Noyes s prediction, the Noyes relationship is emerging as a rather general expression for predicting (or at least comparing) FcP values The interesting feature about the reasonably good linear t between kd/kc and m1/2/r2 for the radical cage pairs derived from the model complexes in the preceding paragraph is that Noyes derived his expression for spherical particles,55 58 yet the various radicals discussed above are decidedly not spherical The explanation for the good t lies in the reason for the dependence of FcP on r 2.

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The parameter r 2 is proportional to the surface area of a particle, which in turn is proportional to the number of interactions a particle has with solvent molecules The more interactions a particle has with the solvent, the greater the viscous drag and consequently the slower the rate of diffusion (and hence the inverse dependence of kd/kc on r 2) This analysis suggests that Noyes s expression can be modi ed by replacing r 2 with the particle s surface area that is, kd/kc m1/2/radical surface area In fact, plots of kd/kc vs m1/2/surface area were linear53 As a further test, plots of kd/kc vs m1/2/surface area were also linear for the (CpCH2CH2OSiR3)2Mo2(CO)6 molecules (R Me, i-Pr, n-Pr, n-Hx) This result provided further support for the modi ed Noyes expression.

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The signi cance of being able to use a particle s surface area in the Noyes expression is that the expression becomes useful for nonspherical particles that is, it becomes possible to use the Noyes expression for virtually all radicals, not just spherical ones These results show that FcP increases as the length of the chain on a radical center increases In turn, this explains why the quantum yields for the photochemical degradation of polymers (and long-chain molecules, in general) decrease as the chains get longer Undoubtedly, after a certain chain length is reached, no changes in FcP will likely be observed due to the considerable inertia of the radicals In such cases, the chain movements will be local that is, radical diffusion out of the cage or recombination in the cage will occur by segmental motion of the chain end and.

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