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If the rates of the electrode reactions are large and the system is fairly close to equilibrium (the electrode potential is quite close to the reversible electrode potential), then the right-hand sides of Eqs (5.4.3) and (5.4.4) correspond to the difference between two large numbers whose absolute values are much larger than those of the left-hand sides. The left-hand side can then be set approximately equal to zero, A:ccOx k3icKcd ~ 0, and in view of Eqs (5.2.14) and (5.2.17),



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(5A5)





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The process begins when the user composes data and hands it to a process on his or her computer for network processing Assume that the user has composed an email and pressed the Send key in her email application Behind the scenes, the email application will take the data the user has written and place an SMTP protocol header in front of it (the SMTP header is marked in darkest gray in Figure 113) The mail application will then make a request to a TCP process running on the user s computer to send the SMTP data TCP will accept the SMTP information, possibly breaking it into discrete units of information, and place a TCP header in front of the SMTP header.

which is a form of the Nernst equation. The electrode reaction thus proceeds approximately at equilibrium (this is often termed a 'reversible' electrode process). When A o or A >0, then cRed 0 or cOx *0. A limiting current is then > formed on the polarization curve that is independent of the electrode potential (see page 286). If the initial concentration, e.g. of the oxidized

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281 component, equals c , then the equations of the limiting diffusion current density yd are obtained for various types of diffusion and convective diffusion; these equations follow from Eqs (2.5.8), (2.7.12) and (2.7.17) after multiplication of the right-hand sides by nF. In the general case, the initial concentration of the oxidized component equals Cox ar*d that of the reduced component c Red . If the appropriate differential equations are used for transport of the two electroactive forms (see Eqs 2.5.3 and 2.7.16) with the corresponding diffusion coefficients, then the relationship between the concentrations of the oxidized and reduced forms at the surface of the electrode (for linear diffusion and simplified convective diffusion to a growing sphere) is given in the form (5.4.6) For the sake of simplicity, it will further be assumed that c Red = 0. For the boundary conditions (5.4.5), i.e. the prescribed ratio of the concentrations of the two forms, we may use the transformation -A(D Ox /D Red ) 1/2 cg 1 + A(DOx/DRed)l/2 Together with the boundary condition (5.4.5) and relationship (5.4.6), this yields the partial differential equation (2.5.3) for linear diffusion and Eq. (2.7.16) for convective diffusion to a growing sphere, where D = DOx and c = CoJ[l +k(DOx/DRed)1/2]. As for linear diffusion, the limiting diffusion current density is given by the Cottrell equation

This process continues in like manner with TCP handing its information to the IP process that places an IP header in front of the TCP header (the IP header is marked in lightest gray in Figure 113), after which the IP process passes its information to the Ethernet process so that the Ethernet header can be placed in front of the IP header Now that all of the protocol headers have been inserted one in front of the other, the packet is ready for transmission across the network In the figure, each router in the path would remove the Layer 2/Ethernet header, read the Layer 3/IP header information in order to know what next hop to forward the packet to, place a new Layer 2 header onto the packet, and forward the packet out of the appropriate interface.

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