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Determine the VCI for the VC that leads to the ATM destination address Segment the datagram into cells at the sending side of the VC (ie, at the entry router), and reassemble the cells into the original datagram at the receiving side of the VC (ie, at the exit router)



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Seki et al (1993) developed a command surface concept, which uses the azobenzene derivatives bound on the Langmuir Blodgett (LB) lms to control the orientation of the liquid crystal molecules on the lm surfaces by the photoswitching of the azobenzene moieties Maeda et al (2006) extended this concept to control the adsorption properties of mesoporous silica materials by reversible photoswitching of the azobenzene moieties anchored on the pore surfaces A UV/visible spectra study con rmed that the azobenzene moieties isomerized from trans to cis conformation under UV (l = 365 nm) light irradiation at 101C and the reverse isomerization (cis to trans) occurred under visible (l = 436 nm) light irradiation Both isomerization processes saturated after 3 5 min.

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Although the azobenzene moieties isomerized from cis to trans in the dark because of the lower energy of the trans form, especially at elevated temperatures, it was veri ed that up to 85% cis conformation was retained while standing at 01C for 24 h after UV light irradiation It should be possible to measure the adsorption desorption isotherms of the azobenzene-modi ed mesoporous materials and compare the difference of the sorption isotherms between trans and cis conformations However, neither Brinker s nor Maeda s groups observed a signi cant difference in the nitrogen sorption isotherms at 77 K One possible reason is that the probe molecules may be too small to discriminate the slight difference between the two conformations.

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The first sub-task listed above is straightforward The interface at the sending side maintains a table that maps ATM addresses to VCIs Because we are assuming that the VCs are permanent, this table is up-todate and static (If the VCs were not permanent, then an ATM signalling protocol would be needed to dynamically establish and tear down the VCs) The second, task, merits careful One approach is to use IP fragmentation, as discussed in Section 44 With IP fragmentation, the sending router would first fragment the original datagram into fragments, with each fragment being no more than 48 bytes, so that the fragment could fit into the payload of the ATM cell But this fragmentation approach has a big problem -- each IP fragment typically has 20 bytes of header, so that an ATM cell carrying a fragment would have 25 bytes of "overhead" and only 28 bytes of useful information As we shall see in Section 584, the ATM standard provides a more efficient way to segment and reassemble a datagram Recall from Section 110 that ATM has three layers: the physical layer, the ATM layer, and the ATM adaptation layer We now provide a brief introduction into these layers We will then return to issue just raised: How does ATM efficiently segment and reassemble IP datagrams that are sent across an ATM backbone

Instead of the chronoamperometry method employed by Brinker and coworkers to demonstrate the photocontrolled mass transport through the azobenzene-modi ed mesoporous silica membranes, Maeda and coworkers designed a liquid-phase adsorption experiment using 1,4,8,11,15,18,22,25-octabutoxy29H-phthalocyanine (OBPc, B23 nm in diameter) as the molecular probe to demonstrate the photoswitching of adsorption of OBPc on the azobenzenemodi ed pore surfaces In this experiment, the azobenzene-modi ed MSU-H nanoparticles were suspended in an organic solvent containing speci c amounts of OBPc molecular probes under alternating irradiation of UV and visible light It was con rmed that the concentration of the unadsorbed OBPc molecules increased under UV light irradiation and decreased under visible light irradiation.

The physical layer is concerned with sending an ATM cell over a single physical link As shown in Figure 59-2, the physical layer has two sublayers: the Physical Medium Dependent (PMD) Sublayer and the Transmission Convergence (TC) Sublayer Sublayer Transmission Convergence (TC) Sublayer Physical Medium Dependent (PMD) Sublayer Responsibilites Idle Cell Insertion Cell Delineation Transmission Frame Adaptation Physical Medium Bit voltages and timings Frame structure

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