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At the same time, SRG could be readily inscribed onto the spin-coated layers of the same polymer (Lee et al, 2000) Some light-induced surface modulation was also observed for PBACT-AC and PBANT-AC polyelectrolytes (Fig 28) multilayers lms The SRG amplitude was really small, which corresponds quite well with the spin-coated lm of PBANT-AC that also yielded only 85-nm deep SRG (Wang et al, 2004b) Similar results (16-nm amplitude after ca 40-min writing) were obtained for PA AZ CA (Fig 28) layers (He et al, 2004) For PAA-AZ LbL multilayers, any surface modulations have been observed (Wang et al, 2004a) Also, in this case, one cannot exclude that holographic writing conditions were not optimized For polyelectrolyte PS-119 (Fig 28), a dependence of recording rate on pH upon lm preparation similar to that discussed earlier for photoorientation has been found (Zucolotto et al, 2004b).



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Our second scenario is only slightly different from scenario 1 Suppose now that the FTP user has purchased "platinum service" (ie, high priced) Internet access from its ISP, while the audio user has purchased cheap, low-budget Internet service that costs only a minuscule fraction of platinum service Should the cheap user's audio packets be given priority over FTP packets in this case Arguably not In this case, it would seem more reasonable to distinguish packets on the basis of the sender's IP address More generally, we see that it is necessary for a router to classify packets according to some criteria This then calls for a slight modification to principle 1: Principle 1: Packet classification allows a router to distinguish among packets belonging to different classes of traffic Explicit packet marking is one way in which packets may be distinguished However, the marking carried by a packet does not, by itself, mandate that the packet will receive a given quality of service Marking is but one mechanism for distinguishing packets The manner in which a router distinguishes among packets by treating them differently is a policy decision





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Gratings of 26- and 12-nm depth were obtained after 2-h writing in the lms produced at pH 4 and pH 10, respectively It was associated with higher free volume available in lms produced at low pH When the same azobenzene-containing polyelectrolyte (PS-119) was alternated by charged dendrimers (dos Santos, 2006), higher ef ciency for low generation dendrimer was obtained (SRG amplitude of 30 nm) However, all these values were rather small, which bring the question about what might have been the reason for the low ef ciency of the grating formation in LbL systems In the authors opinion, it is closely related to the mechanisms of grating formation in these systems Is it the light-driven motion of chromophores dragging the inert polymer chains by means of ionic interactions in adjacent layers (Zucolotto et al.

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Suppose now that somehow (by use of mechanisms that we will study in subsequent sections), the router knows it should give priority to packets from the 1 Mbps audio application Since the outgoing link speed is 15 Mbps, even though the FTP packets receive lower priority, they will still, on average, receive 05 Mbps of transmission service But what happens if the audio application starts sending packets at a rate of 15 Mbps or higher (either maliciously or due to an error in the application) In this case, the FTP packets will starve, ie, will not receive any service on the R1-to-R2 link Similar problems would occur if multiple applications (eg, multiple audio calls), all with the same priority, were sharing a link's bandwidth; one non-compliant flow could degrade and ruin the performance of the other flows Ideally, one wants a degree of isolation among flows, in order to protect one flow from another misbehaving flow This then is a second underlying principle the provision of QoS guarantees

via an absorbent material such as silica gel to prevent condensation of moisture on the window. Moisture is condensed from the air as it ows through the gel, and the latent heat given up by the condensing moisture increases the air temperature. Molecular sieves can also be used to remove moisture from air. These are absorbent materials which are used to sieve out the large water molecules from the air in the same way as the molecular sieve oxygen concentrators described later in this chapter remove the large gas molecules and impurities from air to leave almost pure oxygen.

, 2004a), whereas the latter suppresses the reversible isomerization of azobenzene and, at the same time, the con nement to the layers hinders any translation motion Or are there other mechanisms, such as photodegradation (bleaching) (He et al, 2000), that may dominate the formation of grating Nevertheless, the applied approach, demonstrating the inscription of SRG in materials with ionic interactions, presents a new insight into physics of lightinduced mass transport in azobenzene-based materials The importance of this approach is particularly enhanced by the possibility of the unique, molecularlevel control over the material properties (Oliveira et al, 2005; Halabieh et al, 2004)..

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