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moment for the trans isomer than the cis isomer (Simmons et al, 2007), should not be used because of the opposite change in dipole moment upon UV light illumination Another consideration also does not favor the use of azobenzene derivatives with strong electron-donor and electron-acceptor groups This pattern of substitution on azobenzene usually results in overlap of the absorption of transazobenzene (p-p*) with that of cis-azobenzene (n-p*), in the 440 460 nm region Not only does the cis isomer have a fast thermally activated relaxation back to the trans isomer, photons absorbed by trans-azobenzene, inducing the trans cis isomerization, can also be signi cantly absorbed by cis-azobenzene that induces the reverse cis trans isomerization The consequence of the fast thermal relaxation of cisazobenzene and the simultaneous photoisomerization in the two directions is that few azobenzene moieties in the cis form can stay.



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We conclude this section by mentioning that firewalls are by no means a panacea for all security problems They introduce a tradeoff between the degree of communication with the outside world and level of security Because filters can't stop spoofing of IP addresses and port numbers, filters often use an all or nothing policy (for example, banning all UDP traffic) Gateways can have software bugs, allowing attackers to penetrate them Also, firewalls or even less effective if the internal users have wireless communication with the external world For these reasons and others, firewalls remain controversial, with many security experts and network administrators being reluctant to use them References Two excellent references are [Chapman 1995][Cheswick 1994] Readers are also encouraged to read white papers in the Web sites for major manufacturers of firewalls (eg, [Checkpoint 1999]) [Cert 1999] CERT, "CERT Summaries," http://wwwcertorg/summaries/ [Chapman 1995] DE Chapman and ED Zwicky, "Building Internet Firewalls," O'Reilly and Associates, Sebastopol, CA, 1995 [Cheswick 1994] WR Cheswick and S M Bellovin, "Firewalls and Internet Security," AddisonWesley, Reading, MA, 1994 [Checkpoint 1999] Checkpoint Software Technologies Ltd homepage, http://wwwcheckpointcom [Newman 1998] D Newman, H Holzbar, M Carter, "Firewalls: Tough Enough", Data Communications Magazine, April, 1998





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Obviously, for light-controllable polymer micelles, a bistable photoswitch is preferred As far as azobenzene is concerned, its derivatives that can undergo a thorough trans cis isomerization upon UV light illumination and have thermally stable cis isomer are mostly interesting From the above analysis, using azobenzene BCPs, a signi cant increase in dipole moment accompanying the trans cis isomerization of the chromophore under UV light can increase the entire polarity of the hydrophobic polymer block and, consequently, shift the hydrophilic hydrophobic balance in the direction thermodynamically unfavorable to the micellar association Although the micellar association is very sensitive to the balance, such a shift may not be necessarily enough to cause the dissociation of BCP micelles; other factors need to be taken into consideration This can be illustrated using a classical small-molecule surfactant as example.

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The anionic surfactants of CH3(CH2)nNHCOO has a cmc sensitive to the hydrophilic hydrophobic balance; the cmc is 18 10 4 mol dm 3 for n=13, while it is reduced by an order to 18 10 5 mol dm 3 for n=15 (longer hydrocarbon tail) (Everett DH, 1988) Now, imagine a micellar solution of the surfactant with n=15 exposed to light, if somehow two methylene groups were removed from the hydrocarbon tail, the micelles would be dissociated if the surfactant concentration in solution was below 18 10 4 mol dm 3 (cmc of the surfactant with n=13), while they would remain if the surfactant concentration was above this cmc This simple example points to the fact that an important shift in the hydrophilic hydrophobic balance alone may not be enough to result in the dissociation of the micelles and that other conditions need to be ful lled.

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As will be discussed later, this indeed is the case for the micelles formed by azobenzenecontaining BCPs In order to achieve an effective dissociation under UV light, a signi cant increase in the dipole moment for azobenzene while converting from the trans to the cis isomer should be conjugated with a hydrophilic block that is weakly hydrophilic, yet enough to induce the formation of BCP micelles in a selective solvent (Tong et al, 2005) The rst BCP micelles exhibiting reversible light-induced control in dissociation and formation were prepared using azobenzene BCPs (Tong et al, 2005; Wang et al, 2004) More important is the fact that inspired by the principles revealed from these studies on azobenzene BCPs using other chromophores, photosensitive BCP micelles with more effective light-induced.

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