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For a stoichiometric feed concentration of acetic acid instead, the optimal resin capacity was calculated as 5 mEq g 1, which is the original Amberlyst 15 resin Further optimization, including also the feed concentration of acetic acid as a decision variable, yielded an eluent requirement of ca 3 mol methanol per mol methyl acetate for a 5 mEq g 1 resin and 60:40 acetic acid:methanol feed stream (Fig 617) The steep increase of the eluent requirement with decreasing resin capacity can be investigated in more detail by analyzing the key adsorptive and reaction parameters The key reaction parameter is clearly the reaction rate constant, which increases linearly with the ion-exchange capacity of the resin Higher reaction rates clearly enhance SMBR efficiency and reduce eluent requirement.





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As mentioned above, in each section of the SMBR, a specific task must be fulfilled and certain binary selectivities can be chosen as key adsorption parameters to explain the separation behavior in each section In section I, the heavy product (water) must be desorbed by the eluent (methanol) from the ion-exchange resin, and therefore a low selectivity between water and methanol is desirable in order to reduce the methanol flow rate in this section as much as possible In section IV, the light component (methyl acetate) is removed from the eluent stream, and consequently a low-selectivity methanol/methyl acetate is advantageous In sections II and III, the products water and methyl acetate are separated and a high-selectivity water/ methyl acetate is therefore beneficial.

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It s important to understand that the error checking feature is not perfect. In fact, it s not even close to perfect. In other words, you can t assume that you have an error-free worksheet simply because Excel does not identify any potential errors! Also, be aware that this error checking feature won t catch a very common type of error that of overwriting a formula cell with a value.

The selectivity of acetic acid to methyl acetate and the water/acetic acid selectivity should also be high in order to permit an easy separation of acetic acid from the products which in turn allows the residence time of acetic acid to be increased and the conversion to be raised The influence of the ion-exchange capacity on these key binary selectivities is shown graphically in Fig 618..

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