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Use this form to upload a local PDF file and convert the PDF file to Word (DOCX, DOC, RTF) file. 1. Click "Choose File" button (different web browser may have different button name such as "browse..."), a browse window will open, select a local Adobe PDF file and click "Open" button.
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electrophile will be governed by the magnitude of the coe cient at the particular atomic position. Polarization of the HOMO away from the point of attachment of the X substituent directs electrophilic attack to that carbon. Attack may also be directed to X itself in certain cases, although this is usually reversible and may have no net consequences. The X-substituted ole n p system is isoelectronic to that of the allyl anion (Figure 5.2). The polarization and energy of the p bond can be deduced by averaging the HOMOs and HOMO energies of the ole n and allyl anion:



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Philanthropic organizations should remain cognizant of the private inurement doctrine.77 Pursuant to this doctrine, a transaction between the organization and a person who is an insider with respect to it can, if the terms and conditions of the transaction are not reasonable, cause the organization to lose or be denied federal tax-exempt status. An illustration of this is payment of excessive compensation to a key employee.





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and elastin bres, and the vascular bed. Like adipocytes, SVF cells in the primordial fat pad are derived from mesenchymal stem cells and various other cells with phenotypes also found in bone marrow; some marrow-derived precursors may also arrive via the circulation. SVF cells make important contributions to the development and function of adipose tissue. The CD34 /CD31 fraction that contains preadipocytes also includes endothelial cells; we have already mentioned the crucial importance of normal vascularization of fat, and the possible role of the endothelium in attracting marrow-derived adipocyte precursors to home into fat pads. The SVF also contains numerous immune cells, which can be isolated using antibody-coated microbeads, FACS and other techniques. In human adipose tissue, the number of resident macrophages was found to correlate with BMI (Weisberg et al., 2003; Curat et al., 2004; Cl ment et al., 2004; Cancello et al., 2005, 2006), and a similar correlation has been observed in various mouse obesity models (Weisberg et al., 2003; Xu et al., 2003). Signi cant numbers of T lymphocytes occur in the SVF of rodents (Caspar-Bauguil et al., 2005), and T lymphocytes accumulate in the fat pads of obese subjects (Wu et al., 2007). Preferential in ltration into intra-abdominal versus subcutaneous fat has been observed, with approximately twice as many lymphocytes being present in omental as compared with subcutaneous depots. The immune activities of the increased number of both macrophages and T lymphocytes may in uence preadipocyte and adipocyte functions, as well as contributing to the generalized chronic in ammatory state that characterizes obesity.

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Select the radio button to share this printer and enter a share name in the box provided. Windows will attempt to enter a name that is being used locally, but this can be changed as needed. For this example, it a high-speed laser printer connected to Flo the secretary s computer, and other users in the department would like access to that print resource, so a share name may be something like flo printer. Other computer users on the network can then go to Control Panel and select Printers and Faxes and then Add a Printer. They may either browse the network for Flo s printer or enter the name directly, as discussed in the le sharing section. For the sake of this example, the name may appear as \\flo pc\flo printer, where flo pc is the server name of the computer and flo printer is the share name for the laser printer sitting by her computer. If needed, the IP address assigned to Flo s computer can be used in place of a server name.

SELECT ename, deptno, WHERE ( (deptno=10 and sal < OR (deptno=20 and sal < OR (deptno=40 and sal < ) OR comm<1400 ORDER BY ename sal FROM emp

the HOMO to the LUMO. The photochemical correlation shown in Figure 14.5a suggests that if the reactants are in their lowest excited state, then the product cyclobutane would also be formed in its lowest excited state. This is considered to be a photochemically allowed reaction. This should be contrasted with the situation depicted in Figure 14.5b, where the lowest excited state of reactants correlates with a highly excited state of the product cyclohexene. Thus the Diels Alder reaction would not proceed with the observed stereochemistry p 4s p 2s under photolysis conditions. This does not imply that a diene and an ole n will not react under these conditions, but it does suggest that the mechanism will be other than the thermally allowed route. The p 2s p 2s unsensitized photodimerization of cis- and trans-2-butene has been carried out and shown to proceed with complete stereospeci city [301]. Another well-studied case involves the p 2s p 2s photochemical conversion of norbornadiene to quadricyclene [302], possibly as a system for the chemical storage of solar energy.

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