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On approaching to a distance equal to their diameters (0.276 nm), water molecules (jU = 6.23 x 10~28 C cm) form a quite stable entity with potential energy Udd= 3.32X 10~20J = 0.2eV. If a comparably large univalent ion approaches a dipolar water molecule (\q'\ = 1.6 x 10~19C), the absolute energy value is almost four times larger, that is Uid= -1.18 x 10"19 J = 0.7 eV. If one water molecule in liquid water is replaced in the tetrahedral lattice by an uncharged particle of the same dimensions, then the four closest water molecules suffice to retain the original arrangement. If the new particle has a sufficiently large charge, e.g. positive, then the arrangement must change. Two water molecules are bonded more strongly than previously and the other two must rotate their negative 'end' towards the cation (Fig. 1.4). Thus, depending on the size and charge of the ion, the original arrangement can either be retained or a new, strong structure can be formed, or some state between these two extremes emerges. The



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9a. what is the difference between the output from a show... command versus an info... command 9b. Experiment with creating a physical interface and leaving out either the IP address or the port. Other than the name, how many additional items need to be configured for the interface to be operational 9c. Experiment to find out if an interface can be both admin and operationally Up/Up on one side and not the other. what are the requirements for an interface to be admin and operationally Up/Up 9d. Notice that all names in the output above are surrounded by quotation ( ) marks. The rule is that quotation marks are only necessary if the name contains a space. Experiment to see what happens if you try to configure an interface named loopback Test without using surrounding quotes. The following table provides a convenient reference of the requirements for configuring L3 interfaces:





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Fig. 1.4 Disturbing effect of a cation (void circle) on water structure. Molecules 1 and 2 show reversed orientation

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ordering of the liquid can be completely destroyed if the ion disturbs the original arrangement without forming a new one Negative hydration numbers are then obtained for some ions, as if these salts produced 'depolymerization' of the water structure This phenomenon is termed structure breaking The destructive effect increases with increasing ionic radius, eg in the order Li+<Na+<Rb+<Cs+, Cl", NO 3 " < Br" < r < C1O3and with increasing charge, eg in the order Li+<Be2+<Al3+ Figure 15 schematically depicts a partially distorted water structure A region is formed in the immediate vicinity of the ion where the water molecules are electrostatically bonded so strongly to the ion that they lose the ability to rotate The value of the permittivity thus decreases sharply (to 6-7 compared to a value of 7854 at 25 C in pure water) This region is termed the primary hydration sphere.

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10. Check the route tables of the CE and PE routers. Notice the routes that now appear in the route table, and take note of their protocol type. There should be exactly one route for each interface that is operationally Up: four for PE1 and three for CE1 and PE2.

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Depending on conditions, regions further from the centre of the ion contain a more or less distorted water structure and regions even further away retain the original structure It should be realized that the structure breaking results in an increase in the entropy of the system and thus in a decrease in its Gibbs energy (according to the well-known relationship at constant temperature, AG = AH TAS) If a more complex dissolved particle contains both charged (polar) and uncharged (non-polar) groups, then this entropy factor becomes important The structure of the solvent remains intact at the 'non-polar surface' of the particle In order to increase the entropy of the system this 'surface' must be as small as possible to decrease the region where the solvent structure is unbroken.

*B:PE1>config>router# show router route-table =============================================================== Route Table (Router: Base) =============================================================== Dest Prefix Type Proto Age Pref Next Hop[Interface Name] Metric --------------------------------------------------------------140.10.0.1/32 Local Local 01h11m25s 0 system 0 140.10.0.11/32 Local Local 00h00m45s 0 loopbackTest 0 140.10.0.96/30 Local Local 00h44m49s 0 toPE2 0 140.10.0.100/30 Local Local 00h28m42s 0 toCE1 0 --------------------------------------------------------------No. of Routes: 4 =============================================================== *B:PE1>config>router#

This is achieved by a close approach of two particles with their non-polar regions or by a conformation change resulting in a contact of non-polar regions in the molecule These, mainly entropic, effects termed hydrophobic (in general solvophobic).

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