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The limitation of the problem to a single energy profile is depicted in Fig. 5.5 as a symbolic dependence of the potential energy of the reacting system on the reaction coordinate. If, according to the Marcus theory, the system passes rapidly through the region of intersection of the potential energy curves for the initial state (R) and for the final state (P), then there is insufficient time for the electron transfer, so that the system mostly passes through the intercept into the upper part of the R curve; the probability of electron transfer is low, characterizing non-adiabatic electron transfer. When the system passes through the intercept region slowly (i.e. with a slow change in the configuration of the atomic nuclei), then electron transfer almost always occurs. This is characteristic of adiabatic electron transfer. The slow process is termed reorganization of the system. According to Marcus, the following contributions are involved: (a) Changes in the energy and entropy of the internal structure of the species as a result of changes in the bond lengths and angles (b) Changes in the size of the reacting particle (c) Changes in the vibrational and orientational polarization of the vicinity of the particle Further considerations will deal only with the simple case where the slow process involves a change in the solvation shell of the reacting species, e.g. for the Fe3+(aq) and Fe2+(aq) ions. The applicability of the assumption of an adiabatic process depends on the vibration frequency of the slow system (i.e. of the solvation shell). The

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3c At this point in time, how many routes are in PE1 s routing table Explain your answer PE1 should have 8 routes in total: 4 local routes plus 2 routes from CE1 via OSPF and 2 routes from PE2 via BgP 3d How does PE1 learn about CE1 s interfaces: through OSPF or BgP, or both what does the routing table say Explain your answer PE1 only has routes to CE1 from OSPF The routing table confirms the OSPF information Parts 3a and 3b of this question confirmed that no routes are received from CE1 via BgP 4a Have the two PE routers exchanged any route information No, the PE routers have not exchanged any new routes since adding the BgP export policy on CE1 4b what is the preference value for BgP routes By default, the preference value for BgP routes is 170.

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criterion is the quantity kT/hco, where fi is Planck's constant divided by 2n and co is the angular frequency of vibration At laboratory temperature kT/hco =* 10~13 For the vibration of the solvent shell co kT/h while for the vibration of the electron shell co kT/ft, which means that the electron transfer can be considered as adiabatic Under these conditions, a further simplification is possible as the whole problem can be treated classically, the vibrations of the solvation shell being discussed in terms of a set of classical harmonic oscillations.

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By default, the preference value for OSPF routes is either 10 (internal) or 150 (external) 4c At this point in time, how many routes are in the routing table Explain your answer There are no changes to the number of routes in any of the three routers No new routes resulted from adding the BgP export policy on CE1 4d How does PE1 learn about CE1 s interfaces: through OSPF, BgP, or both what does the routing table say Explain your answer PE1 has routes to CE1 from both the OSPF and BgP RIB Only the OSPF routes appear in the routing table As explained in Question 7b from the previous section, the preference value causes OSPF routes to be chosen over BgP routes when equivalent routes exist in both protocols 5a Does either router have routes to the other s system and loopback interfaces Yes.

In order to describe properly the electron transfer between the electroactive ion B z+ and the electrode Bz+(l) + e(m)-*B (2 - 1)+ (l) the following assumptions are necessary: (a) The solvation shells of the ions Bz+ and B (2 ~ 1)+ vibrate harmonically with identical frequency co> so that the potential energies of both solvation shells can be expressed by identical mutually shifted parabolas (b) Quantum-mechanical effects need not be considered in the region around the activated complex (in the vicinity of the intersection of the two parabolas) (c) The kinetic energy of the system is identical in the initial and final states (d) Only electrons from the Fermi level in the electrode and from the redox system in the solution in the ground state participate in the electrode reaction (e) The concentrations of the ions Bz+ and B (2 ~ 1)+ are equal to unity.

CE1 and PE2 both have routes to the other router s system interface The reason for this is that although there is no OSPF adjacency between PE1 and PE2, PE1 still has the DistributeLB export policy applied to the OSPF process Therefore, the IP address of the link between PE1 PE2 is known by CE1 and the next hop can be resolved In a typical real-world scenario, however, a more.

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