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Optical isomerism in polymers, see Stereoisomerism in polymers; Stereoselective polymerization Organometallic polymer, 172 174, 330, 595 599 Orlon, 308 Oscillating metallocene, 675 676 Ostwald ripening, 367 Oxidative coupling, 146 148, 165 166 Oxonium ion, 554 555 Oxycarbocation, 560 PAI, see Polyamideimide Paired ion, 373 374 PAM resin, 775 PAN, see Polyacrylonitrile Paracyclophane, 311 Parent polymer, 287 288 Parylene, 312 Particle nucleation, 354 Particle number, 354 356, 362 363 Particle size distribution, 365 366 Patterns of reactivity scheme, 503 505 PBI, see Polybenzimidazole PBO, see Polybenzoxazole PBT, see Poly(butylene terephthalate) PC, see Polycarbonate PCTFE, see Polychlorotri uoroethylene PDI, see Polydispersity index PE, see Polyethylene Pearl polymerization, 298 Pebax,143 PEEK, see Polyetheretherketone PEI, see Polyetherimide PEK, see Polyetherketone PEN, see Poly(ethylene 2,6-naphthalate) Pentad, 636 Penultimate effect in copolymerization, 513 515. See also Chain copolymerization; Copolymerization equation; Monomer Reactivity Ratio Penultimate model, see Markov model Penultimate unit, 513 Peroxides, 210 211, 216 217, 742 744 Persistent radical effect, 315 316 PES, see Polyethersulfone PET, see Poly(ethylene terephthalate) Petrothene, 302 Phase-transfer catalyst, 770 Phenol-formaldehyde polymer, 6, 120 126 Phenolic polymer, see Phenol-formaldehyde polymer Phenoxy-imine chelate initiator, 688 689 Phillips initiator, 696 697



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where Cl and C2 are two constants. The question is: How do you match these two constants This is a first-order differential equation and there must be only one integration constant, so there must be a relation between Cl and C2. If we use (F.39) or (F.41), we conclude that this relation should be (F.45)





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Philprene, 529 Phosphonitrilic chloride, 597 Phosphorus-containing cyclic ester, 599 600 Photobleaching, 220, 224 Photochemical reaction: cationic polymerization, 379 380 crosslinking, 569 graft polymerization, 756 radical polymerization, 218 224, 273 Photoinitiated polymerization, see Photochemical reaction Photoresist, 219 Photosensitizer, 218 219 Phthalocyanine polymer, 172 173 Physical crosslinking, 142, 437 PI, see Polyimide Pickup mechanism, 288 Placement, 203 Plasma polymerization, 227 Plastic, 34 36 Plasticization, 305 Plasticizer, 306 Plexiglas, 308 PLP-SEC, 264 265, 267 269 PMMA, see Poly(methyl methacrylate) Polar effect: radical copolymerization, 497 500 radical polymerization, 248 249, 261 263 Polyacetaldehyde, 627 Polyacetal, 444 449 Polyacetylene, 164, 684 Polyacrylamide, 308 309, 450 451 Polyacrylate, 307 308 Polyacrylic acid, 308 309 Polyacrylonitrile, 308, 751 Polyalkylsilyne, 174 Poly(amic acid), 151 Polyamide, 97 101 Polyamideimide, 153 154 Polyamidoamine dendrimer, 177 180 Poly(6-aminocaproic acid), 569 577 Polyaniline, 165 Polyaramide, 99 101 Polyarylate, 141 142 Polybenzimidazole, 159 161 Polybenzoxazole, 161 162 Polybenzothiazole, 161 162 Polybutadiene, 310, 627, 633, 699 Polybutene, 410 Poly(1-butene), 698 Poly(butylene terephthalate), 96 Poly(E-caprolactam), 569 577 Poly(E-caprolactone), 548 569

If, on the other hand, we regard the delta function as the limit of a very thin and large barrier, we easily find that [252] (F.46)

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Polycarbonate, 2, 96 97 Polycarbosilane, 174 Polychloroprene, 533, 699 Poly(chlorotri uoroethylene), 309 Polycondensation, 9 Polycycloalkene, 589 591 Polycycloalkyne, 591 Poly(dichlorophosphazene), 597 598 Polydicyclopentadiene, 591 1,4-Poly-1,3-diene: crosslinking, 738 744 cyclization, 695, 749 halogenation, 748 749 polymerization, 689 695 stereoisomerism, 627 631 Poly(2,6-dimethylphenylene oxide), see Poly(p-phenylene oxide) Polydimethylsiloxane, see Polysiloxane Polydimethylsilylene, 174 Polydiphenylsilylene, 174 Polydispersity index, 22 23. See also Molecular weight distribution Polyepichlorohydrin, 569 Polyesteramide, 154 Polyesteri cation, 49 53, 92 96, 118 120. See also Polyester; Step polymerization Polyester: alkyd, 118 120, 737 738 crosslinked, 118 120, 737 738, 531 532 linear, 2, 92 97 polycarbonate, 96 97 unsaturated, 118 120, 531 532 Polyesterimide, 154 Polyether, 146 150 Polyether glycol, 568 Polyetherimide, 153 Polyetherketone, 149 150 Polyetheretherketone, 149 150 Polyethersulfone, 149 150 Polyethylene: branching, 250 255 chlorination, 749 chlorosulfonation, 750 copolymers, 530 531 crosslinking, 742 743 crystallinity, 28 29 high density, 530,696 697 linear low density, 530, 696 697 low density, 300 302, 530 Poly(ethylene glycol), 765 766 Polyethyleneimine, 586 587 Poly(ethylene 2,6-naphthalate), 96 Poly(ethylene oxide), 569

Which one is correct, (F.45) or (F.46) We can easily see that (F.46) is the correct relation because as Griffiths and Walborn [252] pointed out, (F.42) can be solved directly (F.47) where c is the single integration constant. Can we trace down the mistake in the steps that lead to (F.39) and (FA1) We notice that if we apply the steps that lead us to (FA1) to the product of four step functions instead of just two as in (FAO), we find that

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