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1,3-Placement occurs through an isomerization process similar to that responsible for 3,1placement in propene polymerization (Sec 8-5c-1) 1,3-Placement is also observed with nickel and palladium a-diimine initiators [Sacchi et al, 2001] (Sec 8-8b) 1,3-Placement has not been reported for other cycloalkene polymerizations Cyclohexene does not polymerize by either route except when it is part of a bicyclic structure as in norbornene Stereochemistry in the ROMP of norbornene is complicated since the polymer, LXVI in Sec 7-8, has possibilities of isomerism at both the ring and the double bond Most polymerizations by the typical ROMP initiators yield cis stereochemistry at the cyclopentane ring with varying amounts of cis and trans placements at the double bond [Ivin, 1987] Metallocene initiators yield predominantly double-bond polymerization with 1,2-placement [Janiak and Lassahn, 2001] Little is known about the R/S isomerism (ie.



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Dec 7, 2017 · See that example for information on how to open an Excel workbook, write data into it, and save it. Note that before you can use the Excel interop library, you need to open the Add References dialog, click the .NET tab, and select Microsoft.Office.Interop.Excel (or whatever version you have installed on your system.)

In principle, TJ can be any complex number. The boundary conditions on the cavity walls, however, detennine what kind of complex number TJ can be. First, we show that TJ must be a negative real number in the case of a perfect cavity. For that, we notice that if we take the scalar product of (A. I0) with X and integrate, the right-hand side of (A. 10) will be a positive number times TJ. Now look at the left-hand side of (A.IO). As V . X = 0, we can replace V 2X by - V 1\ (V 1\ X), so that

, erythro and threo ditactic structures are possible) at the stereocenters that result from double-bond polymerization Cycloheptene and higher cycloalkenes undergo only ROMP; double-bond polymerization does not occur because the larger rings can accommodate the double bond without being highly strained..

dV(X)2 = -





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Styrene is slightly polar compared to ethylene and a-ole ns. The lack of a strongly polar functional group allows styrene to undergo highly (>95 98% ) isoselective polymerization

dV X . [V 1\ (V 1\ X)]

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with many of the heterogeneous traditional Ziegler Natta initiators effective for a-ole ns [Longo et al., 1990; Pasquon et al., 1989; Soga et al., 1988]. Highly (>95 98%) syndiotactic polystyrene is obtained using a variety of soluble titanium initiators such as CpTiCl3 and Cp2 TiCl2 , and various substituted cyclopentadienyl analogs with MAO [Coates, 2000; Ishihara et al., 1988; Minieri et al., 2001a,b; Pellecchia et al., 1987; Po and Cardi, 1996; Schellenberg and Tomotsu, 2002; Schwecke and Kaminsky, 2001; Zambelli et al., 1989]. Zirconium initiators are also useful, but their activity is lower than that of the titanium initiators. Partially isotactic polystyrenes are obtained with n-butyllithium in toluene at 40 C and the heterogeneous al n initiator (allylsodium sodium isopropoxide NaCl) in hexane at 20 C [Braun et al., 1960; Kern, 1960]. Partially syndiotactic polystyrenes are obtained with many different initiators, including n-butyllithium in toluene at 25 C and higher temperatures and cesium naphthalene in toluene at 0 C or THF at 78 C [Kawamura et al., 1982]. There is little tendency toward stereoselectivity with cationic initiators, although polymerizations of a-methylstyrene by BF3, SnCl4 , and other Lewis acids give moderate syndioselectivity [Wicke and Elgert, 1977].

[~I\ (V 1\ X)], -

Acetylene is polymerized to polyacetylene [IUPAC: poly(ethene-1,2-diyl)] by Ziegler Natta initiators such as titanium tetraisobutoxide with triethylaluminum [Ito et al., 1974; Shelburne and Baker, 1987; Shirakawa, 2001; Theophilou and Naarman, 1989]. Polymerization at

dV (V 1\ X)2

8-67

~ (V 1\ X)],

18 C yields a polymer with 90% cis content; polymerization at 100 C yields a polymer with >90% trans content. Polyacetylene, doped with an oxidant or a reductant, showed promise as a polymeric semiconductor [Chien, 1984]. That promise was not realized because of the oxidative instability of polyacetylene and emergence of cheaper and more stable polymer systems (Sec. 2-14j). Various substituted acetylenes such as phenylacetylene have also been studied [Kanki et al., 2002; Misumi et al., 2000].

18 D

"---v---'

8-7 COPOLYMERIZATION Statistical copolymerization occurs among ethylene and various a-ole ns [Baldwin and Ver Strate, 1972; Cooper, 1976; Pasquon et al., 1967; Randall, 1978]. The reactivities of monomers in copolymerization generally parallel their homopolymerization behavior: ethylene > propene > 1-butene > 1-hexene [Soga et al., 1989]. Table 8-7 shows monomer reactivity ratios for several comonomer pairs. Monomer reactivity ratios vary somewhat with the identity of the initiator in some systems, but the available data are insuf cient to understand the general trends [Dankova and Waymouth, 2003; Fan et al., 2001; Kaminsky and Freidanck, 2002; Wigum et al., 2000]. Among the structural parameters that might affect r1 and r2 are differences in monomer accessabilities to the initiator sites and differences that result from steric or electronic factors. One might also anticipate that r1 and r2 are affected by solvent polarity whereby a coordinating solvent competes preferentially with one of the monomers for the initiator sites [Forlini et al., 2002; Sacchi et al., 2003].

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Convert Excel (XLSX, XLS) to PDF in C# / VB.NET - GemBox
NET code. ' Convert Excel (XLSX) to PDF. ExcelFile.Load("Workbook.xlsx").Save(​"Workbook.pdf"). For a more detailed example, see Convert Excel to PDF in C# ...

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This is a package of an Example Project for NpoiExcel. As a free C# excel API, it can enable developers to edit, copy, create, print and convert Excel files which ...












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